BODIPY star-shaped molecules as solid state colour converters for visible light communications

Chiranthika Dimali Amarasinghe Vithanage; Pavlos Manousiadis; Muhammad Tariq Sajjad; Sujan Rajbhandari; Hyunchae Chun; Clara Orofino; Diego Cortizo-Lacalle; Alexander Kanibolotsky; Grahame  Faulkner; Neil Findlay; Dominic O'Brien; Peter Skabara; Ifor David William Samuel; Graham Alexander Turnbull

doi:10.1063/1.4953789

BODIPY star-shaped molecules as solid state colour converters for visible light communications

Chiranthika Dimali Amarasinghe Vithanage, Pavlos Manousiadis, Muhammad Tariq Sajjad, Sujan Rajbhandari, Hyunchae Chun, Clara Orofino, Diego Cortizo-Lacalle, Alexander Kanibolotsky, Grahame Faulkner, Neil Findlay, Dominic O'Brien, Peter Skabara, Ifor David William Samuel, Graham Alexander Turnbull

Research output: Contribution to journal › Article › peer-review

Abstract

In this paper we study a family of solid-state, organic semiconductors for visible light communications. The star-shaped molecules have a boron-dipyrromethene (BODIPY) core with a range of side arm lengths which control the photophysical properties. The molecules emit red light with photoluminescence quantum yields ranging from 22 - 56 %. Thin films of the most promising BODIPY molecules were used as a red colour converter for visible light communications. The film enabled colour conversion with a modulation bandwidth of 73 MHz, which is 16 times higher than of a typical phosphor used in LED lighting systems. A data rate of 370 Mbit/s was demonstrated using On-Off keying modulation in a free space link with a distance of ~15 cm.

Original language	English
Article number	013302
Journal	Applied Physics Letters
Volume	109
Issue number	1
DOIs	https://doi.org/10.1063/1.4953789
Publication status	Published - 6 Jul 2016

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© 2016, AIP Publishing. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at scitation.aip.org
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© 2016, AIP Publishing. This work is made available online in accordance with the publisher’s policies. This is the final published version of the work which was originally published at http://dx.doi.org/10.1063/1.4953789
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Ultra-parallel visable light communicati: UK Visible Light Communications
Samuel, I. D. W. (PI) & Turnbull, G. (CoI)
EPSRC
1/10/12 → 28/02/17
Project: Standard

Data underpinning - BODIPY star-shaped molecules as solid-state colour converters for visible light communications
Vithanage, C. D. A. (Creator), Manousiadis, P. (Creator), Sajjad, M. T. (Creator), Rajbhandari, S. (Creator), Chun, H. (Creator), Orofino, C. (Creator), Cortizo-Lacalle, D. (Creator), Kanibolotsky, A. (Creator), Faulkner, G. (Creator), Findlay, N. (Creator), O'Brien, D. (Creator), Skabara, P. (Creator), Samuel, I. D. W. (Creator) & Turnbull, G. A. (Creator), University of St Andrews, 15 Sept 2016
DOI: 10.17630/20163d03-6cc2-43b6-915c-d271f5220454
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Vithanage, C. D. A., Manousiadis, P., Sajjad, M. T., Rajbhandari, S., Chun, H., Orofino, C., Cortizo-Lacalle, D., Kanibolotsky, A., Faulkner, G., Findlay, N., O'Brien, D., Skabara, P., Samuel, I. D. W., & Turnbull, G. A. (2016). BODIPY star-shaped molecules as solid state colour converters for visible light communications. Applied Physics Letters, 109(1), Article 013302. https://doi.org/10.1063/1.4953789

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title = "BODIPY star-shaped molecules as solid state colour converters for visible light communications",

abstract = "In this paper we study a family of solid-state, organic semiconductors for visible light communications. The star-shaped molecules have a boron-dipyrromethene (BODIPY) core with a range of side arm lengths which control the photophysical properties. The molecules emit red light with photoluminescence quantum yields ranging from 22 - 56 %. Thin films of the most promising BODIPY molecules were used as a red colour converter for visible light communications. The film enabled colour conversion with a modulation bandwidth of 73 MHz, which is 16 times higher than of a typical phosphor used in LED lighting systems. A data rate of 370 Mbit/s was demonstrated using On-Off keying modulation in a free space link with a distance of ~15 cm.",

author = "Vithanage, {Chiranthika Dimali Amarasinghe} and Pavlos Manousiadis and Sajjad, {Muhammad Tariq} and Sujan Rajbhandari and Hyunchae Chun and Clara Orofino and Diego Cortizo-Lacalle and Alexander Kanibolotsky and Grahame Faulkner and Neil Findlay and Dominic O'Brien and Peter Skabara and Samuel, {Ifor David William} and Turnbull, {Graham Alexander}",

note = "We thank EPSRC for financial support from the UP-VLC Programme Grant (EP/K00042X/1). I.D.W.S. and P.J.S. are Royal Society Wolfson Research Merit Award holders. The research data supporting this publication can be accessed at http://dx.doi.org/10.17630/20163d03-6cc2-43b6-915c-d271f5220454.",

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Vithanage, CDA, Manousiadis, P, Sajjad, MT, Rajbhandari, S, Chun, H, Orofino, C, Cortizo-Lacalle, D, Kanibolotsky, A, Faulkner, G, Findlay, N, O'Brien, D, Skabara, P, Samuel, IDW & Turnbull, GA 2016, 'BODIPY star-shaped molecules as solid state colour converters for visible light communications', Applied Physics Letters, vol. 109, no. 1, 013302. https://doi.org/10.1063/1.4953789

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T1 - BODIPY star-shaped molecules as solid state colour converters for visible light communications

AU - Vithanage, Chiranthika Dimali Amarasinghe

AU - Manousiadis, Pavlos

AU - Sajjad, Muhammad Tariq

AU - Rajbhandari, Sujan

AU - Chun, Hyunchae

AU - Orofino, Clara

AU - Cortizo-Lacalle, Diego

AU - Kanibolotsky, Alexander

AU - Faulkner, Grahame

AU - Findlay, Neil

AU - O'Brien, Dominic

AU - Skabara, Peter

AU - Samuel, Ifor David William

AU - Turnbull, Graham Alexander

N1 - We thank EPSRC for financial support from the UP-VLC Programme Grant (EP/K00042X/1). I.D.W.S. and P.J.S. are Royal Society Wolfson Research Merit Award holders. The research data supporting this publication can be accessed at http://dx.doi.org/10.17630/20163d03-6cc2-43b6-915c-d271f5220454.

PY - 2016/7/6

Y1 - 2016/7/6

N2 - In this paper we study a family of solid-state, organic semiconductors for visible light communications. The star-shaped molecules have a boron-dipyrromethene (BODIPY) core with a range of side arm lengths which control the photophysical properties. The molecules emit red light with photoluminescence quantum yields ranging from 22 - 56 %. Thin films of the most promising BODIPY molecules were used as a red colour converter for visible light communications. The film enabled colour conversion with a modulation bandwidth of 73 MHz, which is 16 times higher than of a typical phosphor used in LED lighting systems. A data rate of 370 Mbit/s was demonstrated using On-Off keying modulation in a free space link with a distance of ~15 cm.

AB - In this paper we study a family of solid-state, organic semiconductors for visible light communications. The star-shaped molecules have a boron-dipyrromethene (BODIPY) core with a range of side arm lengths which control the photophysical properties. The molecules emit red light with photoluminescence quantum yields ranging from 22 - 56 %. Thin films of the most promising BODIPY molecules were used as a red colour converter for visible light communications. The film enabled colour conversion with a modulation bandwidth of 73 MHz, which is 16 times higher than of a typical phosphor used in LED lighting systems. A data rate of 370 Mbit/s was demonstrated using On-Off keying modulation in a free space link with a distance of ~15 cm.

U2 - 10.1063/1.4953789

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VL - 109

JO - Applied Physics Letters

JF - Applied Physics Letters

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M1 - 013302

ER -

BODIPY star-shaped molecules as solid state colour converters for visible light communications

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