Bis(phosphine) derivatives of diamines

Mireia R i Zubiri; Heather L Milton; David John Cole-Hamilton; Alexandra Martha Zoya Slawin; John Derek Woollins

doi:10.1016/j.poly.2003.11.048

Bis(phosphine) derivatives of diamines

Mireia R i Zubiri, Heather L Milton, David John Cole-Hamilton, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis, oxidation and coordination chemistry of new bis(aminophosphines) based on diamines is demonstrated. Ph2PN(CH2Ph)CH2CH2(CH2Ph)NPPh2, (Pr2PN)-Pr-i(CH2Ph)CH2CH2(CH2Ph)(NPPr2)-Pr-i, Ph2PNH(C10H6)(2)NHPPh2, Ph2PNH(C10H6) (C6H4)NHPPh2 were prepared and tested in the hydroformylation of hex-1-to give aldehydes with poor selectivity (up to 1:b=2.5:1) to the desired linear products. Modelling calculations were performed for all ligands. R-2 groups enlarge the natural bite angle when going from R-2 = Ph-2 to R-2 = Pr-i(2) which are more bulky. Most of the ligands seem to be rigid (with flexibility ranges of 25degrees-46degrees). Four demonstrative X-ray structures are reported. (C) 2003 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	693-399
Number of pages	7
Journal	Polyhedron
Volume	23
Issue number	4
DOIs	https://doi.org/10.1016/j.poly.2003.11.048
Publication status	Published - 12 Feb 2004

Keywords

ligand
catalysis
X-ray structure
complex
RHODIUM-CATALYZED HYDROFORMYLATION
COORDINATION CHEMISTRY
MOLECULAR-STRUCTURE
PLATINUM COMPLEXES
LIGANDS
PHOSPHINE
DIPHOSPHINES
BULKY
MECHANISM
OCT-1-ENE

Access to Document

10.1016/j.poly.2003.11.048

Cite this

@article{8c8f32520cfb4e83a79bb0a9f976a02d,

title = "Bis(phosphine) derivatives of diamines",

abstract = "The synthesis, oxidation and coordination chemistry of new bis(aminophosphines) based on diamines is demonstrated. Ph2PN(CH2Ph)CH2CH2(CH2Ph)NPPh2, (Pr2PN)-Pr-i(CH2Ph)CH2CH2(CH2Ph)(NPPr2)-Pr-i, Ph2PNH(C10H6)(2)NHPPh2, Ph2PNH(C10H6) (C6H4)NHPPh2 were prepared and tested in the hydroformylation of hex-1-to give aldehydes with poor selectivity (up to 1:b=2.5:1) to the desired linear products. Modelling calculations were performed for all ligands. R-2 groups enlarge the natural bite angle when going from R-2 = Ph-2 to R-2 = Pr-i(2) which are more bulky. Most of the ligands seem to be rigid (with flexibility ranges of 25degrees-46degrees). Four demonstrative X-ray structures are reported. (C) 2003 Elsevier Ltd. All rights reserved.",

keywords = "ligand, catalysis, X-ray structure, complex, RHODIUM-CATALYZED HYDROFORMYLATION, COORDINATION CHEMISTRY, MOLECULAR-STRUCTURE, PLATINUM COMPLEXES, LIGANDS, PHOSPHINE, DIPHOSPHINES, BULKY, MECHANISM, OCT-1-ENE",

author = "{i Zubiri}, {Mireia R} and Milton, {Heather L} and Cole-Hamilton, {David John} and Slawin, {Alexandra Martha Zoya} and Woollins, {John Derek}",

year = "2004",

month = feb,

day = "12",

doi = "10.1016/j.poly.2003.11.048",

language = "English",

volume = "23",

pages = "693--399",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

number = "4",

}

TY - JOUR

T1 - Bis(phosphine) derivatives of diamines

AU - i Zubiri, Mireia R

AU - Milton, Heather L

AU - Cole-Hamilton, David John

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, John Derek

PY - 2004/2/12

Y1 - 2004/2/12

N2 - The synthesis, oxidation and coordination chemistry of new bis(aminophosphines) based on diamines is demonstrated. Ph2PN(CH2Ph)CH2CH2(CH2Ph)NPPh2, (Pr2PN)-Pr-i(CH2Ph)CH2CH2(CH2Ph)(NPPr2)-Pr-i, Ph2PNH(C10H6)(2)NHPPh2, Ph2PNH(C10H6) (C6H4)NHPPh2 were prepared and tested in the hydroformylation of hex-1-to give aldehydes with poor selectivity (up to 1:b=2.5:1) to the desired linear products. Modelling calculations were performed for all ligands. R-2 groups enlarge the natural bite angle when going from R-2 = Ph-2 to R-2 = Pr-i(2) which are more bulky. Most of the ligands seem to be rigid (with flexibility ranges of 25degrees-46degrees). Four demonstrative X-ray structures are reported. (C) 2003 Elsevier Ltd. All rights reserved.

AB - The synthesis, oxidation and coordination chemistry of new bis(aminophosphines) based on diamines is demonstrated. Ph2PN(CH2Ph)CH2CH2(CH2Ph)NPPh2, (Pr2PN)-Pr-i(CH2Ph)CH2CH2(CH2Ph)(NPPr2)-Pr-i, Ph2PNH(C10H6)(2)NHPPh2, Ph2PNH(C10H6) (C6H4)NHPPh2 were prepared and tested in the hydroformylation of hex-1-to give aldehydes with poor selectivity (up to 1:b=2.5:1) to the desired linear products. Modelling calculations were performed for all ligands. R-2 groups enlarge the natural bite angle when going from R-2 = Ph-2 to R-2 = Pr-i(2) which are more bulky. Most of the ligands seem to be rigid (with flexibility ranges of 25degrees-46degrees). Four demonstrative X-ray structures are reported. (C) 2003 Elsevier Ltd. All rights reserved.

KW - ligand

KW - catalysis

KW - X-ray structure

KW - complex

KW - RHODIUM-CATALYZED HYDROFORMYLATION

KW - COORDINATION CHEMISTRY

KW - MOLECULAR-STRUCTURE

KW - PLATINUM COMPLEXES

KW - LIGANDS

KW - PHOSPHINE

KW - DIPHOSPHINES

KW - BULKY

KW - MECHANISM

KW - OCT-1-ENE

UR - http://www.scopus.com/inward/record.url?scp=1042301079&partnerID=8YFLogxK

UR - http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6TH8-4BJ7475-5&_user=1026342&_coverDate=02%2F12%2F2004&_alid=178396022&_rdoc=6&_fmt=full&_orig=search&_cdi=5276&_sort=d&_st=4&_docanchor=&_acct=C000050565&_version=1&_urlVersion=0&_userid=1026342&md5=6d4d93fa9524d3c19077b47b08588a15

U2 - 10.1016/j.poly.2003.11.048

DO - 10.1016/j.poly.2003.11.048

M3 - Article

SN - 0277-5387

VL - 23

SP - 693

EP - 399

JO - Polyhedron

JF - Polyhedron

IS - 4

ER -

Bis(phosphine) derivatives of diamines

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this