Bis[mu-6-amino-3-methyl-5-nitroso-pyrimidine-2,4(1H,3H)-dionato-kappa O-3(4),N-5 : O-5]-di-mu-aqua-bis{diaqua[6-amino-3-methyl-5-nitrosopyri-midine-2,4(1H,3H)-dionato-kappa N-2(1),O-2]strontium(II)}: centrosymmetric dimers containing nine-coordinate Sr, linked by multiple hydrogen bonds into a three-dimensional framework

J N  Low; P  Arranz; R  Cuesta; M D  Gutierrez; C  Glidewell

doi:10.1107/S0108270102021492

Bis[mu-6-amino-3-methyl-5-nitroso-pyrimidine-2,4(1H,3H)-dionato-kappa O-3(4),N-5 : O-5]-di-mu-aqua-bis{diaqua[6-amino-3-methyl-5-nitrosopyri-midine-2,4(1H,3H)-dionato-kappa N-2(1),O-2]strontium(II)}: centrosymmetric dimers containing nine-coordinate Sr, linked by multiple hydrogen bonds into a three-dimensional framework

J N Low, P Arranz, R Cuesta, M D Gutierrez, C Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The title complex, [Sr-2 (C5H5N4O3)(4) (H2O)(6)], forms centrosymmetric dimers in which one water ligand bridges two Sr centres and in which one of the anionic ligands is bidentate and bonded to just one Sr atom, and the other is tridentate and bridges the two Sr centres within the dimer. The dimeric units are linked by an extensive series of O-H...O, O-H...N and N-H...O hydrogen bonds to form a complex three-dimensional framework.

Original language	English
Number of pages	4
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	59
DOIs	https://doi.org/10.1107/S0108270102021492
Publication status	Published - Jan 2003

Keywords

POLYMER

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Low, J. N., Arranz, P., Cuesta, R., Gutierrez, M. D., & Glidewell, C. (2003). Bis[mu-6-amino-3-methyl-5-nitroso-pyrimidine-2,4(1H,3H)-dionato-kappa O-3(4),N-5 : O-5]-di-mu-aqua-bis{diaqua[6-amino-3-methyl-5-nitrosopyri-midine-2,4(1H,3H)-dionato-kappa N-2(1),O-2]strontium(II)}: centrosymmetric dimers containing nine-coordinate Sr, linked by multiple hydrogen bonds into a three-dimensional framework. Acta Crystallographica Section C-Crystal Structure Communications, 59. https://doi.org/10.1107/S0108270102021492

Low, J N ; Arranz, P ; Cuesta, R et al. / Bis[mu-6-amino-3-methyl-5-nitroso-pyrimidine-2,4(1H,3H)-dionato-kappa O-3(4),N-5 : O-5]-di-mu-aqua-bis{diaqua[6-amino-3-methyl-5-nitrosopyri-midine-2,4(1H,3H)-dionato-kappa N-2(1),O-2]strontium(II)}: centrosymmetric dimers containing nine-coordinate Sr, linked by multiple hydrogen bonds into a three-dimensional framework. In: Acta Crystallographica Section C-Crystal Structure Communications. 2003 ; Vol. 59.

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title = "Bis[mu-6-amino-3-methyl-5-nitroso-pyrimidine-2,4(1H,3H)-dionato-kappa O-3(4),N-5 : O-5]-di-mu-aqua-bis{diaqua[6-amino-3-methyl-5-nitrosopyri-midine-2,4(1H,3H)-dionato-kappa N-2(1),O-2]strontium(II)}: centrosymmetric dimers containing nine-coordinate Sr, linked by multiple hydrogen bonds into a three-dimensional framework",

abstract = "The title complex, [Sr-2 (C5H5N4O3)(4) (H2O)(6)], forms centrosymmetric dimers in which one water ligand bridges two Sr centres and in which one of the anionic ligands is bidentate and bonded to just one Sr atom, and the other is tridentate and bridges the two Sr centres within the dimer. The dimeric units are linked by an extensive series of O-H...O, O-H...N and N-H...O hydrogen bonds to form a complex three-dimensional framework.",

keywords = "POLYMER",

author = "Low, {J N} and P Arranz and R Cuesta and Gutierrez, {M D} and C Glidewell",

year = "2003",

month = jan,

doi = "10.1107/S0108270102021492",

language = "English",

volume = "59",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

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Low, JN, Arranz, P, Cuesta, R, Gutierrez, MD & Glidewell, C 2003, 'Bis[mu-6-amino-3-methyl-5-nitroso-pyrimidine-2,4(1H,3H)-dionato-kappa O-3(4),N-5 : O-5]-di-mu-aqua-bis{diaqua[6-amino-3-methyl-5-nitrosopyri-midine-2,4(1H,3H)-dionato-kappa N-2(1),O-2]strontium(II)}: centrosymmetric dimers containing nine-coordinate Sr, linked by multiple hydrogen bonds into a three-dimensional framework', Acta Crystallographica Section C-Crystal Structure Communications, vol. 59. https://doi.org/10.1107/S0108270102021492

Bis[mu-6-amino-3-methyl-5-nitroso-pyrimidine-2,4(1H,3H)-dionato-kappa O-3(4),N-5 : O-5]-di-mu-aqua-bis{diaqua[6-amino-3-methyl-5-nitrosopyri-midine-2,4(1H,3H)-dionato-kappa N-2(1),O-2]strontium(II)}: centrosymmetric dimers containing nine-coordinate Sr, linked by multiple hydrogen bonds into a three-dimensional framework. / Low, J N ; Arranz, P ; Cuesta, R et al.
In: Acta Crystallographica Section C-Crystal Structure Communications, Vol. 59, 01.2003.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Bis[mu-6-amino-3-methyl-5-nitroso-pyrimidine-2,4(1H,3H)-dionato-kappa O-3(4),N-5 : O-5]-di-mu-aqua-bis{diaqua[6-amino-3-methyl-5-nitrosopyri-midine-2,4(1H,3H)-dionato-kappa N-2(1),O-2]strontium(II)}: centrosymmetric dimers containing nine-coordinate Sr, linked by multiple hydrogen bonds into a three-dimensional framework

AU - Low, J N

AU - Arranz, P

AU - Cuesta, R

AU - Gutierrez, M D

AU - Glidewell, C

PY - 2003/1

Y1 - 2003/1

N2 - The title complex, [Sr-2 (C5H5N4O3)(4) (H2O)(6)], forms centrosymmetric dimers in which one water ligand bridges two Sr centres and in which one of the anionic ligands is bidentate and bonded to just one Sr atom, and the other is tridentate and bridges the two Sr centres within the dimer. The dimeric units are linked by an extensive series of O-H...O, O-H...N and N-H...O hydrogen bonds to form a complex three-dimensional framework.

AB - The title complex, [Sr-2 (C5H5N4O3)(4) (H2O)(6)], forms centrosymmetric dimers in which one water ligand bridges two Sr centres and in which one of the anionic ligands is bidentate and bonded to just one Sr atom, and the other is tridentate and bridges the two Sr centres within the dimer. The dimeric units are linked by an extensive series of O-H...O, O-H...N and N-H...O hydrogen bonds to form a complex three-dimensional framework.

KW - POLYMER

U2 - 10.1107/S0108270102021492

DO - 10.1107/S0108270102021492

M3 - Article

SN - 1600-5759

VL - 59

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

Low JN, Arranz P, Cuesta R, Gutierrez MD, Glidewell C. Bis[mu-6-amino-3-methyl-5-nitroso-pyrimidine-2,4(1H,3H)-dionato-kappa O-3(4),N-5 : O-5]-di-mu-aqua-bis{diaqua[6-amino-3-methyl-5-nitrosopyri-midine-2,4(1H,3H)-dionato-kappa N-2(1),O-2]strontium(II)}: centrosymmetric dimers containing nine-coordinate Sr, linked by multiple hydrogen bonds into a three-dimensional framework. Acta Crystallographica Section C-Crystal Structure Communications. 2003 Jan;59. doi: 10.1107/S0108270102021492