Bis(diphenylmethylphosphine-kappa P)(disulfur-dinitrido-kappa(2),N,S)platinum(II) dichloromethane solvate

Benjamin D. Read; Alexandra M. Z. Slawin; J. Derek Woollins

doi:10.1107/S1600536807006344

Bis(diphenylmethylphosphine-kappa P)(disulfur-dinitrido-kappa(2),N,S)platinum(II) dichloromethane solvate

Benjamin D. Read
, Alexandra M. Z. Slawin
, J. Derek Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, [Pt(N2S2)(C13H13P)(2)](CH2Cl2)-C-., contains Pt-II in a square-planar coordination. The five-membered PtS2N2 ring contains two short and one long S-N bonds. Interestingly, the S-N bond lengths have a different pattern from those in the PMe2Ph analogue and one of the published PPh3 analogues, but are comparable with those in most other systems containing the disulfurdinitride anion.

Original language	English
Number of pages	2
Journal	Acta Crystallographica. Section E, Structure reports online
Volume	63
DOIs	https://doi.org/10.1107/S1600536807006344
Publication status	Published - Mar 2007

Keywords

SULFUR NITROGEN COMPLEXES
RAY CRYSTAL-STRUCTURE
STACKING COMPOUNDS
PD

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title = "Bis(diphenylmethylphosphine-kappa P)(disulfur-dinitrido-kappa(2),N,S)platinum(II) dichloromethane solvate",

abstract = "The title compound, [Pt(N2S2)(C13H13P)(2)](CH2Cl2)-C-., contains Pt-II in a square-planar coordination. The five-membered PtS2N2 ring contains two short and one long S-N bonds. Interestingly, the S-N bond lengths have a different pattern from those in the PMe2Ph analogue and one of the published PPh3 analogues, but are comparable with those in most other systems containing the disulfurdinitride anion.",

keywords = "SULFUR NITROGEN COMPLEXES, RAY CRYSTAL-STRUCTURE, STACKING COMPOUNDS, PD",

author = "Read, \{Benjamin D.\} and Slawin, \{Alexandra M. Z.\} and Woollins, \{J. Derek\}",

year = "2007",

month = mar,

doi = "10.1107/S1600536807006344",

language = "English",

volume = "63",

journal = "Acta Crystallographica. Section E, Structure reports online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - Bis(diphenylmethylphosphine-kappa P)(disulfur-dinitrido-kappa(2),N,S)platinum(II) dichloromethane solvate

AU - Read, Benjamin D.

AU - Slawin, Alexandra M. Z.

AU - Woollins, J. Derek

PY - 2007/3

Y1 - 2007/3

N2 - The title compound, [Pt(N2S2)(C13H13P)(2)](CH2Cl2)-C-., contains Pt-II in a square-planar coordination. The five-membered PtS2N2 ring contains two short and one long S-N bonds. Interestingly, the S-N bond lengths have a different pattern from those in the PMe2Ph analogue and one of the published PPh3 analogues, but are comparable with those in most other systems containing the disulfurdinitride anion.

AB - The title compound, [Pt(N2S2)(C13H13P)(2)](CH2Cl2)-C-., contains Pt-II in a square-planar coordination. The five-membered PtS2N2 ring contains two short and one long S-N bonds. Interestingly, the S-N bond lengths have a different pattern from those in the PMe2Ph analogue and one of the published PPh3 analogues, but are comparable with those in most other systems containing the disulfurdinitride anion.

KW - SULFUR NITROGEN COMPLEXES

KW - RAY CRYSTAL-STRUCTURE

KW - STACKING COMPOUNDS

KW - PD

UR - https://www.scopus.com/pages/publications/33947245485

U2 - 10.1107/S1600536807006344

DO - 10.1107/S1600536807006344

M3 - Article

SN - 1600-5368

VL - 63

JO - Acta Crystallographica. Section E, Structure reports online

JF - Acta Crystallographica. Section E, Structure reports online

ER -

Bis(diphenylmethylphosphine-kappa P)(disulfur-dinitrido-kappa(2),N,S)platinum(II) dichloromethane solvate

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