Bis(diphenylmethylphosphine-kappa P)(disulfur-dinitrido-kappa(2),N,S)platinum(II) dichloromethane solvate

Benjamin D. Read, Alexandra M. Z. Slawin, J. Derek Woollins

Research output: Contribution to journalArticlepeer-review

Abstract

The title compound, [Pt(N2S2)(C13H13P)(2)](CH2Cl2)-C-., contains Pt-II in a square-planar coordination. The five-membered PtS2N2 ring contains two short and one long S-N bonds. Interestingly, the S-N bond lengths have a different pattern from those in the PMe2Ph analogue and one of the published PPh3 analogues, but are comparable with those in most other systems containing the disulfurdinitride anion.

Original languageEnglish
Number of pages2
JournalActa Crystallographica. Section E, Structure reports online
Volume63
DOIs
Publication statusPublished - Mar 2007

Keywords

  • SULFUR NITROGEN COMPLEXES
  • RAY CRYSTAL-STRUCTURE
  • STACKING COMPOUNDS
  • PD

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