Bis(4-hydroxybenzoato-O)(1,4,8,11-tetraazacyclotetradecane-kappa N-4)-nickel(II): a three-dimensional framework built from O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds

C Glidewell, G Ferguson, R M Gregson, A J Lough

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

The title compound, [Ni(C7H5O3)(2)(C10H24N4)], contains octahedral Ni-II in a centrosymmetric trans configuration with Ni-N distances of 2.0637 (17) and 2.0699 (16) Angstrom and an Ni-O distance of 2.1100 (14) Angstrom. The molecules are linked by a single type of O-H ... O hydrogen bond [O ... O 2.618 (2) Angstrom and O-H ... O 161 degrees] into two-dimensional sheets; a single type of N-H ... O hydrogen bond [N ... O 2.991 (2) Angstrom and N-H ... O 139 degrees] links these sheets into a three-dimensional framework.

Original languageEnglish
Pages (from-to)174-176
Number of pages3
JournalActa Crystallographica Section C-Crystal Structure Communications
Volume56
Publication statusPublished - Feb 2000

Keywords

  • CRYSTAL-STRUCTURE
  • COMPLEXES
  • 1,4,8,11-TETRAAZACYCLOTETRADECANE
  • CYCLAM

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