Bis(2,2'-bipyridine)(5-isothio­cyanato-1,10-phenanthroline)ruthenium(II) bis­(hexa­fluoridophosphate) acetonitrile solvate

Samik Nag; Amlan Kumar Pal; Garry S. Hanan

doi:10.1107/S1600536809035302

Bis(2,2'-bipyridine)(5-isothiocyanato-1,10-phenanthroline)ruthenium(II) bis(hexafluoridophosphate) acetonitrile solvate

Samik Nag, Amlan Kumar Pal, Garry S. Hanan

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, [Ru(C10H8N2)2(C13H7N3S)](PF6)2·CH3CN, was synthesized by the reaction of thiophosgene and bis(2,2'-bipyridine)(1,10-phenanthrolin-5-amine)ruthenium(II) bis(hexafluoridophosphate). The RuII atom adopts a slightly distorted octahedral RuN6 coordinaton formed by four N atoms of two bipyridine ligands and by two N atoms of the 1,10-phenantroline ligand. The isothiocyanate group is almost linear, with an N-C-S angle of 174.4 (6)°. Two of the three hexafluoridophosphate counter-anions are located on inversion centres.

Original language	English
Pages (from-to)	m1184
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	10
DOIs	https://doi.org/10.1107/S1600536809035302
Publication status	Published - 1 Oct 2009

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title = "Bis(2,2'-bipyridine)(5-isothiocyanato-1,10-phenanthroline)ruthenium(II) bis(hexafluoridophosphate) acetonitrile solvate",

abstract = "The title compound, [Ru(C10H8N2)2(C13H7N3S)](PF6)2·CH3CN, was synthesized by the reaction of thiophosgene and bis(2,2'-bipyridine)(1,10-phenanthrolin-5-amine)ruthenium(II) bis(hexafluoridophosphate). The RuII atom adopts a slightly distorted octahedral RuN6 coordinaton formed by four N atoms of two bipyridine ligands and by two N atoms of the 1,10-phenantroline ligand. The isothiocyanate group is almost linear, with an N-C-S angle of 174.4 (6)°. Two of the three hexafluoridophosphate counter-anions are located on inversion centres.",

author = "Samik Nag and Pal, {Amlan Kumar} and Hanan, {Garry S.}",

year = "2009",

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doi = "10.1107/S1600536809035302",

language = "English",

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publisher = "International Union of Crystallography",

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T1 - Bis(2,2'-bipyridine)(5-isothiocyanato-1,10-phenanthroline)ruthenium(II) bis(hexafluoridophosphate) acetonitrile solvate

AU - Nag, Samik

AU - Pal, Amlan Kumar

AU - Hanan, Garry S.

PY - 2009/10/1

Y1 - 2009/10/1

N2 - The title compound, [Ru(C10H8N2)2(C13H7N3S)](PF6)2·CH3CN, was synthesized by the reaction of thiophosgene and bis(2,2'-bipyridine)(1,10-phenanthrolin-5-amine)ruthenium(II) bis(hexafluoridophosphate). The RuII atom adopts a slightly distorted octahedral RuN6 coordinaton formed by four N atoms of two bipyridine ligands and by two N atoms of the 1,10-phenantroline ligand. The isothiocyanate group is almost linear, with an N-C-S angle of 174.4 (6)°. Two of the three hexafluoridophosphate counter-anions are located on inversion centres.

AB - The title compound, [Ru(C10H8N2)2(C13H7N3S)](PF6)2·CH3CN, was synthesized by the reaction of thiophosgene and bis(2,2'-bipyridine)(1,10-phenanthrolin-5-amine)ruthenium(II) bis(hexafluoridophosphate). The RuII atom adopts a slightly distorted octahedral RuN6 coordinaton formed by four N atoms of two bipyridine ligands and by two N atoms of the 1,10-phenantroline ligand. The isothiocyanate group is almost linear, with an N-C-S angle of 174.4 (6)°. Two of the three hexafluoridophosphate counter-anions are located on inversion centres.

U2 - 10.1107/S1600536809035302

DO - 10.1107/S1600536809035302

M3 - Article

SN - 1600-5368

VL - 65

SP - m1184

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 10

ER -

Bis(2,2'-bipyridine)(5-isothio­cyanato-1,10-phenanthroline)ruthenium(II) bis­(hexa­fluoridophosphate) acetonitrile solvate

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Bis(2,2'-bipyridine)(5-isothiocyanato-1,10-phenanthroline)ruthenium(II) bis(hexafluoridophosphate) acetonitrile solvate