Binuclear aroyl and carbamoyl complexes of iron: X-ray crystal structures of [Fe-2(mu :sigma,sigma '-OCR)(2)(CO)(5)(PPh3)] (R = C6H3Me2-2,6, (NPr2)-Pr-i)

S  Anderson; A F  Hill; A M Z  Slawin; A J P  White; D J  Williams

Binuclear aroyl and carbamoyl complexes of iron: X-ray crystal structures of [Fe-2(mu :sigma,sigma '-OCR)(2)(CO)(5)(PPh3)] (R = C6H3Me2-2,6, (NPr2)-Pr-i)

S Anderson
, A F Hill
, A M Z Slawin
, A J P White
, D J Williams

Research output: Contribution to journal › Article › peer-review

Abstract

The syntheses of two bimetallic complexes [Fe-2(mu:sigma,sigma'-OCR)(2)(CO)(5)(PPh3)] [R = C6H3Me2-2,6 (1), (NPr2)-Pr-1 (2)] are described, the latter by a variety of routes. A comparison of the structural effects of the aroyl and carbamoyl. bridging ligands upon the unsymmetrically bridged diiron core follows from crystallographic studies on both complexes.

Original language	English
Pages (from-to)	594-+
Number of pages	5
Journal	Inorganic Chemistry
Volume	37
Issue number	3
Publication status	Published - 9 Feb 1998

Keywords

POLYNUCLEAR METAL-COMPLEXES
MOLECULAR-STRUCTURE
BRIDGING CARBENE
CARBYNE LIGANDS
BETA-DIKETONES
C-ALKYLATION
MOLYBDENUM
CHEMISTRY
DERIVATIVES
SUBSTITUTION

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title = "Binuclear aroyl and carbamoyl complexes of iron: X-ray crystal structures of [Fe-2(mu :sigma,sigma '-OCR)(2)(CO)(5)(PPh3)] (R = C6H3Me2-2,6, (NPr2)-Pr-i)",

abstract = "The syntheses of two bimetallic complexes [Fe-2(mu:sigma,sigma'-OCR)(2)(CO)(5)(PPh3)] [R = C6H3Me2-2,6 (1), (NPr2)-Pr-1 (2)] are described, the latter by a variety of routes. A comparison of the structural effects of the aroyl and carbamoyl. bridging ligands upon the unsymmetrically bridged diiron core follows from crystallographic studies on both complexes.",

keywords = "POLYNUCLEAR METAL-COMPLEXES, MOLECULAR-STRUCTURE, BRIDGING CARBENE, CARBYNE LIGANDS, BETA-DIKETONES, C-ALKYLATION, MOLYBDENUM, CHEMISTRY, DERIVATIVES, SUBSTITUTION",

author = "S Anderson and Hill, \{A F\} and Slawin, \{A M Z\} and White, \{A J P\} and Williams, \{D J\}",

year = "1998",

month = feb,

day = "9",

language = "English",

volume = "37",

pages = "594--+",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society (ACS)",

number = "3",

}

TY - JOUR

T1 - Binuclear aroyl and carbamoyl complexes of iron: X-ray crystal structures of [Fe-2(mu :sigma,sigma '-OCR)(2)(CO)(5)(PPh3)] (R = C6H3Me2-2,6, (NPr2)-Pr-i)

AU - Anderson, S

AU - Hill, A F

AU - Slawin, A M Z

AU - White, A J P

AU - Williams, D J

PY - 1998/2/9

Y1 - 1998/2/9

N2 - The syntheses of two bimetallic complexes [Fe-2(mu:sigma,sigma'-OCR)(2)(CO)(5)(PPh3)] [R = C6H3Me2-2,6 (1), (NPr2)-Pr-1 (2)] are described, the latter by a variety of routes. A comparison of the structural effects of the aroyl and carbamoyl. bridging ligands upon the unsymmetrically bridged diiron core follows from crystallographic studies on both complexes.

AB - The syntheses of two bimetallic complexes [Fe-2(mu:sigma,sigma'-OCR)(2)(CO)(5)(PPh3)] [R = C6H3Me2-2,6 (1), (NPr2)-Pr-1 (2)] are described, the latter by a variety of routes. A comparison of the structural effects of the aroyl and carbamoyl. bridging ligands upon the unsymmetrically bridged diiron core follows from crystallographic studies on both complexes.

KW - POLYNUCLEAR METAL-COMPLEXES

KW - MOLECULAR-STRUCTURE

KW - BRIDGING CARBENE

KW - CARBYNE LIGANDS

KW - BETA-DIKETONES

KW - C-ALKYLATION

KW - MOLYBDENUM

KW - CHEMISTRY

KW - DERIVATIVES

KW - SUBSTITUTION

M3 - Article

SN - 0020-1669

VL - 37

SP - 594-+

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 3

ER -

Binuclear aroyl and carbamoyl complexes of iron: X-ray crystal structures of [Fe-2(mu :sigma,sigma '-OCR)(2)(CO)(5)(PPh3)] (R = C6H3Me2-2,6, (NPr2)-Pr-i)

Abstract

Keywords

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