Abstract
The syntheses of two bimetallic complexes [Fe-2(mu:sigma,sigma'-OCR)(2)(CO)(5)(PPh3)] [R = C6H3Me2-2,6 (1), (NPr2)-Pr-1 (2)] are described, the latter by a variety of routes. A comparison of the structural effects of the aroyl and carbamoyl. bridging ligands upon the unsymmetrically bridged diiron core follows from crystallographic studies on both complexes.
Original language | English |
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Pages (from-to) | 594-+ |
Number of pages | 5 |
Journal | Inorganic Chemistry |
Volume | 37 |
Issue number | 3 |
Publication status | Published - 9 Feb 1998 |
Keywords
- POLYNUCLEAR METAL-COMPLEXES
- MOLECULAR-STRUCTURE
- BRIDGING CARBENE
- CARBYNE LIGANDS
- BETA-DIKETONES
- C-ALKYLATION
- MOLYBDENUM
- CHEMISTRY
- DERIVATIVES
- SUBSTITUTION