Binuclear aroyl and carbamoyl complexes of iron: X-ray crystal structures of [Fe-2(mu :sigma,sigma '-OCR)(2)(CO)(5)(PPh3)] (R = C6H3Me2-2,6, (NPr2)-Pr-i)

S Anderson, A F Hill, A M Z Slawin, A J P White, D J Williams

Research output: Contribution to journalArticlepeer-review

18 Citations (Scopus)

Abstract

The syntheses of two bimetallic complexes [Fe-2(mu:sigma,sigma'-OCR)(2)(CO)(5)(PPh3)] [R = C6H3Me2-2,6 (1), (NPr2)-Pr-1 (2)] are described, the latter by a variety of routes. A comparison of the structural effects of the aroyl and carbamoyl. bridging ligands upon the unsymmetrically bridged diiron core follows from crystallographic studies on both complexes.

Original languageEnglish
Pages (from-to)594-+
Number of pages5
JournalInorganic Chemistry
Volume37
Issue number3
Publication statusPublished - 9 Feb 1998

Keywords

  • POLYNUCLEAR METAL-COMPLEXES
  • MOLECULAR-STRUCTURE
  • BRIDGING CARBENE
  • CARBYNE LIGANDS
  • BETA-DIKETONES
  • C-ALKYLATION
  • MOLYBDENUM
  • CHEMISTRY
  • DERIVATIVES
  • SUBSTITUTION

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