Bilayers in 4-iodo-N-(2-iodo-4-nitrophenyl)benzamide generated by a combination of an N-H...O=C hydrogen bond and two independent iodo-nitro interactions

Christopher Glidewell; JN Low; JMS Skakle; JL Wardell

doi:10.1107/S0108270103021164

Bilayers in 4-iodo-N-(2-iodo-4-nitrophenyl)benzamide generated by a combination of an N-H...O=C hydrogen bond and two independent iodo-nitro interactions

Christopher Glidewell, JN Low, JMS Skakle, JL Wardell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Molecules of the title compound, C13H8I2N2O3, are linked into C(4) chains by a single N-H...O=C hydrogen bond [H...O = 2.10 Angstrom, N...O = 2.832(5) Angstrom and N-H...O = 140degrees]. Two independent two-centre iodo-nitro interactions, both involving the same O atom but different I atoms [I...O = 3.205 (3) and 3.400 (3) Angstrom, and C-I...O = 160.4 (2) and 155.7 (2)degrees], link the hydrogen-bonded chains into bilayers.

Original language	English
Pages (from-to)	o636-o637
Number of pages	2
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	C59
DOIs	https://doi.org/10.1107/S0108270103021164
Publication status	Published - Nov 2003

Keywords

PI-STACKING INTERACTIONS
INTERPLAY
PATTERNS

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10.1107/S0108270103021164

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@article{9c9c22c353d84144a6532c59c43014ff,

title = "Bilayers in 4-iodo-N-(2-iodo-4-nitrophenyl)benzamide generated by a combination of an N-H...O=C hydrogen bond and two independent iodo-nitro interactions",

abstract = "Molecules of the title compound, C13H8I2N2O3, are linked into C(4) chains by a single N-H...O=C hydrogen bond [H...O = 2.10 Angstrom, N...O = 2.832(5) Angstrom and N-H...O = 140degrees]. Two independent two-centre iodo-nitro interactions, both involving the same O atom but different I atoms [I...O = 3.205 (3) and 3.400 (3) Angstrom, and C-I...O = 160.4 (2) and 155.7 (2)degrees], link the hydrogen-bonded chains into bilayers.",

keywords = "PI-STACKING INTERACTIONS, INTERPLAY, PATTERNS",

author = "Christopher Glidewell and JN Low and JMS Skakle and JL Wardell",

year = "2003",

month = nov,

doi = "10.1107/S0108270103021164",

language = "English",

volume = "C59",

pages = "o636--o637",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

}

Bilayers in 4-iodo-N-(2-iodo-4-nitrophenyl)benzamide generated by a combination of an N-H...O=C hydrogen bond and two independent iodo-nitro interactions. / Glidewell, Christopher; Low, JN; Skakle, JMS et al.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. C59, 11.2003, p. o636-o637.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Bilayers in 4-iodo-N-(2-iodo-4-nitrophenyl)benzamide generated by a combination of an N-H...O=C hydrogen bond and two independent iodo-nitro interactions

AU - Glidewell, Christopher

AU - Low, JN

AU - Skakle, JMS

AU - Wardell, JL

PY - 2003/11

Y1 - 2003/11

N2 - Molecules of the title compound, C13H8I2N2O3, are linked into C(4) chains by a single N-H...O=C hydrogen bond [H...O = 2.10 Angstrom, N...O = 2.832(5) Angstrom and N-H...O = 140degrees]. Two independent two-centre iodo-nitro interactions, both involving the same O atom but different I atoms [I...O = 3.205 (3) and 3.400 (3) Angstrom, and C-I...O = 160.4 (2) and 155.7 (2)degrees], link the hydrogen-bonded chains into bilayers.

AB - Molecules of the title compound, C13H8I2N2O3, are linked into C(4) chains by a single N-H...O=C hydrogen bond [H...O = 2.10 Angstrom, N...O = 2.832(5) Angstrom and N-H...O = 140degrees]. Two independent two-centre iodo-nitro interactions, both involving the same O atom but different I atoms [I...O = 3.205 (3) and 3.400 (3) Angstrom, and C-I...O = 160.4 (2) and 155.7 (2)degrees], link the hydrogen-bonded chains into bilayers.

KW - PI-STACKING INTERACTIONS

KW - INTERPLAY

KW - PATTERNS

UR - https://www.scopus.com/pages/publications/0345171453

U2 - 10.1107/S0108270103021164

DO - 10.1107/S0108270103021164

M3 - Article

SN - 0108-2701

VL - C59

SP - o636-o637

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

ER -

Bilayers in 4-iodo-N-(2-iodo-4-nitrophenyl)benzamide generated by a combination of an N-H...O=C hydrogen bond and two independent iodo-nitro interactions

Abstract

Keywords

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