Bidentate Organophosphorus Ligands Formed via P-N Bond Formation: Synthesis and Coordination Chemistry

TQ Ly, John Derek Woollins

Research output: Other contribution

199 Citations (Scopus)

Abstract

This article outlines two related bidentate organophosphorus ligand systems prepared by phosphorus-nitrogen (P-N) bond formation - R-2(E)PNHPR2, RC(E)NHPR2 (E = O, S, or Se) and their derivatives. The focus is on the extensive coordination chemistry exhibited by these systems to transition metals. A brief description of the syntheses of the ligands and metal complexes is given. (C) 1998 Elsevier Science S.A. All rights reserved.

Original languageEnglish
Volume176
Publication statusPublished - Sept 1998

Keywords

  • coordination
  • organophosphorus
  • phosphorus-nitrogen
  • transition metal
  • MOLECULAR-STRUCTURE
  • CRYSTAL-STRUCTURE
  • X-RAY
  • PLATINUM(II) COMPLEXES
  • IMIDODIPHOSPHORIC ACID
  • TETRAPHENYL IMIDODIPHOSPHATE
  • METAL-COMPLEXES
  • SULFUR ANALOGS
  • CHELATE RING
  • SOLID-STATE

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