BECKMANN REARRANGEMENTS IN BICYCLO[2.2.1]HEPTAN-2-ONE OXIMES

P A HUNT, C J MOODY, A M Z SLAWIN, D J WILLIAMS, P L MYERS, C SMITH

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

Although Beckmann rearrangement of norcamphor oxime 1 was unsatisfactory, proceeding in poor yield to give a mixture of lactam products, rearrangement of the E/Z oxime 9, or the pure E-isomer 10, upon treatment with methanesulfonyl chloride and triethylamine, gave the lactam 12 in good yield.

Original languageEnglish
Pages (from-to)831-837
Number of pages7
JournalJournal of the Chemical Society, Perkin Transactions 1
Issue number7
Publication statusPublished - 7 Apr 1992

Keywords

  • LACTAM

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