BECKMANN REARRANGEMENTS IN BICYCLO[2.2.1]HEPTAN-2-ONE OXIMES

P A  HUNT; C J  MOODY; A M Z  SLAWIN; D J  WILLIAMS; P L  MYERS; C  SMITH

BECKMANN REARRANGEMENTS IN BICYCLO[2.2.1]HEPTAN-2-ONE OXIMES

P A HUNT, C J MOODY, A M Z SLAWIN, D J WILLIAMS, P L MYERS, C SMITH

Research output: Contribution to journal › Article › peer-review

Abstract

Although Beckmann rearrangement of norcamphor oxime 1 was unsatisfactory, proceeding in poor yield to give a mixture of lactam products, rearrangement of the E/Z oxime 9, or the pure E-isomer 10, upon treatment with methanesulfonyl chloride and triethylamine, gave the lactam 12 in good yield.

Original language	English
Pages (from-to)	831-837
Number of pages	7
Journal	Journal of the Chemical Society, Perkin Transactions 1
Issue number	7
Publication status	Published - 7 Apr 1992

Keywords

LACTAM

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title = "BECKMANN REARRANGEMENTS IN BICYCLO[2.2.1]HEPTAN-2-ONE OXIMES",

abstract = "Although Beckmann rearrangement of norcamphor oxime 1 was unsatisfactory, proceeding in poor yield to give a mixture of lactam products, rearrangement of the E/Z oxime 9, or the pure E-isomer 10, upon treatment with methanesulfonyl chloride and triethylamine, gave the lactam 12 in good yield.",

keywords = "LACTAM",

author = "HUNT, {P A} and MOODY, {C J} and SLAWIN, {A M Z} and WILLIAMS, {D J} and MYERS, {P L} and C SMITH",

year = "1992",

month = apr,

day = "7",

language = "English",

pages = "831--837",

journal = "Journal of the Chemical Society, Perkin Transactions 1",

issn = "0300-922X",

publisher = "Chemical Society",

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TY - JOUR

T1 - BECKMANN REARRANGEMENTS IN BICYCLO[2.2.1]HEPTAN-2-ONE OXIMES

AU - HUNT, P A

AU - MOODY, C J

AU - SLAWIN, A M Z

AU - WILLIAMS, D J

AU - MYERS, P L

AU - SMITH, C

PY - 1992/4/7

Y1 - 1992/4/7

N2 - Although Beckmann rearrangement of norcamphor oxime 1 was unsatisfactory, proceeding in poor yield to give a mixture of lactam products, rearrangement of the E/Z oxime 9, or the pure E-isomer 10, upon treatment with methanesulfonyl chloride and triethylamine, gave the lactam 12 in good yield.

AB - Although Beckmann rearrangement of norcamphor oxime 1 was unsatisfactory, proceeding in poor yield to give a mixture of lactam products, rearrangement of the E/Z oxime 9, or the pure E-isomer 10, upon treatment with methanesulfonyl chloride and triethylamine, gave the lactam 12 in good yield.

KW - LACTAM

M3 - Article

SN - 0300-922X

SP - 831

EP - 837

JO - Journal of the Chemical Society, Perkin Transactions 1

JF - Journal of the Chemical Society, Perkin Transactions 1

IS - 7

ER -

BECKMANN REARRANGEMENTS IN BICYCLO[2.2.1]HEPTAN-2-ONE OXIMES

Abstract

Keywords

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