Au/Ag-Cocatalyzed Aldoximes to Amides Rearrangement under Solvent- and Acid-Free Conditions

Ruben S. Ramon; Johann Bosson; Silvia Diez-Gonzalez; Nicolas Marion; Steven Patrick Nolan

doi:10.1021/jo902461a

Au/Ag-Cocatalyzed Aldoximes to Amides Rearrangement under Solvent- and Acid-Free Conditions

Ruben S. Ramon, Johann Bosson, Silvia Diez-Gonzalez, Nicolas Marion, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

The gold/silver-cocatalyzed conversion of aldoximes into primary amides is reported. The reaction, which proceeds under neat and acid-free conditions, allows for the conversion of a range of aldoximes, and is a rare example of cooperative catalysis involving well-defined gold species.

Original language	English
Pages (from-to)	1197-1202
Number of pages	6
Journal	The Journal of Organic Chemistry
Volume	75
Issue number	4
DOIs	https://doi.org/10.1021/jo902461a
Publication status	Published - 19 Feb 2010

Keywords

N-HETEROCYCLIC CARBENES
ONE-POT
BECKMANN REARRANGEMENT
ORGANIC TRANSFORMATIONS
CATALYZED CONVERSION
HYDROXIDE CATALYST
HIGHLY EFFICIENT
GOLD CATALYSIS
NITRILES
DEHYDRATION

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10.1021/jo902461a

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title = "Au/Ag-Cocatalyzed Aldoximes to Amides Rearrangement under Solvent- and Acid-Free Conditions",

abstract = "The gold/silver-cocatalyzed conversion of aldoximes into primary amides is reported. The reaction, which proceeds under neat and acid-free conditions, allows for the conversion of a range of aldoximes, and is a rare example of cooperative catalysis involving well-defined gold species.",

keywords = "N-HETEROCYCLIC CARBENES, ONE-POT, BECKMANN REARRANGEMENT, ORGANIC TRANSFORMATIONS, CATALYZED CONVERSION, HYDROXIDE CATALYST, HIGHLY EFFICIENT, GOLD CATALYSIS, NITRILES, DEHYDRATION",

author = "Ramon, {Ruben S.} and Johann Bosson and Silvia Diez-Gonzalez and Nicolas Marion and Nolan, {Steven Patrick}",

year = "2010",

month = feb,

day = "19",

doi = "10.1021/jo902461a",

language = "English",

volume = "75",

pages = "1197--1202",

journal = "The Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society (ACS)",

number = "4",

}

TY - JOUR

T1 - Au/Ag-Cocatalyzed Aldoximes to Amides Rearrangement under Solvent- and Acid-Free Conditions

AU - Ramon, Ruben S.

AU - Bosson, Johann

AU - Diez-Gonzalez, Silvia

AU - Marion, Nicolas

AU - Nolan, Steven Patrick

PY - 2010/2/19

Y1 - 2010/2/19

N2 - The gold/silver-cocatalyzed conversion of aldoximes into primary amides is reported. The reaction, which proceeds under neat and acid-free conditions, allows for the conversion of a range of aldoximes, and is a rare example of cooperative catalysis involving well-defined gold species.

AB - The gold/silver-cocatalyzed conversion of aldoximes into primary amides is reported. The reaction, which proceeds under neat and acid-free conditions, allows for the conversion of a range of aldoximes, and is a rare example of cooperative catalysis involving well-defined gold species.

KW - N-HETEROCYCLIC CARBENES

KW - ONE-POT

KW - BECKMANN REARRANGEMENT

KW - ORGANIC TRANSFORMATIONS

KW - CATALYZED CONVERSION

KW - HYDROXIDE CATALYST

KW - HIGHLY EFFICIENT

KW - GOLD CATALYSIS

KW - NITRILES

KW - DEHYDRATION

UR - http://www.scopus.com/inward/record.url?scp=77249141528&partnerID=8YFLogxK

U2 - 10.1021/jo902461a

DO - 10.1021/jo902461a

M3 - Article

SN - 0022-3263

VL - 75

SP - 1197

EP - 1202

JO - The Journal of Organic Chemistry

JF - The Journal of Organic Chemistry

IS - 4

ER -

Au/Ag-Cocatalyzed Aldoximes to Amides Rearrangement under Solvent- and Acid-Free Conditions

Abstract

Keywords

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Molecular assembly using gold catalysis: Molecular assembly using gold catalysis

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Au/Ag-Cocatalyzed Aldoximes to Amides Rearrangement under Solvent- and Acid-Free Conditions

Abstract

Keywords

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Projects

Molecular assembly using gold catalysis: Molecular assembly using gold catalysis

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