ASYMMETRIC ADDITION OF ORGANOMETALLIC REAGENTS TO O-PHENETHYL ALDOXIMES

P T GALLAGHER, A P LIGHTFOOT, C J MOODY, A M Z SLAWIN

Research output: Contribution to journalComment/debatepeer-review

12 Citations (Scopus)

Abstract

Addition of Grignard and organolithium reagents to O-phenethyl aldoximes in the presence of boron trifluoride etherate gives secondary hydroxylamines in 21-84% yield with 38-95% diastereomeric excess.

Original languageEnglish
Pages (from-to)445-446
Number of pages2
JournalSynlett
Issue number5
Publication statusPublished - May 1995

Keywords

  • ASYMMETRIC ADDITION
  • CHIRAL OXIME ETHER
  • HYDROXYLAMINE
  • ALDEHYDE-SAMP HYDRAZONES
  • ALPHA-IMINO ESTERS
  • OXIME ETHERS

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