Assessing dimerisation degree and cooperativity in a biomimetic small-molecule model by pulsed EPR

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Abstract

Pulsed electron paramagnetic resonance (EPR) spectroscopy is gaining increasing importance as a complementary biophysical technique in structural biology. Here, we describe the synthesis, optimisation, and EPR titration studies of a spin-labelled terpyridine Zn(II) complex serving as a small-molecule model system for tuneable dimerisation.
Original languageEnglish
Pages (from-to)5257-5260
Number of pages4
JournalChemical Communications
Volume51
Issue number25
Early online date8 Jan 2015
DOIs
Publication statusPublished - 28 Mar 2015

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