Aqueous-biphasic hydroformylation of higher alkenes promoted by alkylimidazolium salts

S L Desset; David John Cole-Hamilton; D F Foster

doi:10.1039/b618785d

Aqueous-biphasic hydroformylation of higher alkenes promoted by alkylimidazolium salts

S L Desset
, David John Cole-Hamilton
, D F Foster

Research output: Contribution to journal › Article › peer-review

Abstract

Aqueous-biphasic hydroformylation of higher alkenes (> C-5) can be greatly accelerated by addition of 1-octyl-3-methylimidazolium bromide without affecting the phase separation and with good catalyst retention in the aqueous phase.

Original language	English
Pages (from-to)	1933-1935
Number of pages	3
Journal	Chemical Communications
Volume	2007
Issue number	19
DOIs	https://doi.org/10.1039/b618785d
Publication status	Published - Jan 2007

Keywords

SOLUBLE RHODIUM COMPLEX
CATALYZED HYDROFORMYLATION
OLEFIN HYDROFORMYLATION
CYCLODEXTRINS

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@article{b2ebcac36e8742419847640386f05a54,

title = "Aqueous-biphasic hydroformylation of higher alkenes promoted by alkylimidazolium salts",

abstract = "Aqueous-biphasic hydroformylation of higher alkenes (> C-5) can be greatly accelerated by addition of 1-octyl-3-methylimidazolium bromide without affecting the phase separation and with good catalyst retention in the aqueous phase.",

keywords = "SOLUBLE RHODIUM COMPLEX, CATALYZED HYDROFORMYLATION, OLEFIN HYDROFORMYLATION, CYCLODEXTRINS",

author = "Desset, \{S L\} and Cole-Hamilton, \{David John\} and Foster, \{D F\}",

note = "Referees said {"}The authors are to be congratulated on such a monumental finding{"} and {"}it seems they have found what may well be the universal solution for two-phase homogenous catalysis. If one looks at the number of man years that have been spent in vain world-wide on trying to find an acceptable way to perform two-phase catalysis one can imagine the true significance of this finding.{"}",

year = "2007",

month = jan,

doi = "10.1039/b618785d",

language = "English",

volume = "2007",

pages = "1933--1935",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "19",

}

TY - JOUR

T1 - Aqueous-biphasic hydroformylation of higher alkenes promoted by alkylimidazolium salts

AU - Desset, S L

AU - Cole-Hamilton, David John

AU - Foster, D F

N1 - Referees said "The authors are to be congratulated on such a monumental finding" and "it seems they have found what may well be the universal solution for two-phase homogenous catalysis. If one looks at the number of man years that have been spent in vain world-wide on trying to find an acceptable way to perform two-phase catalysis one can imagine the true significance of this finding."

PY - 2007/1

Y1 - 2007/1

N2 - Aqueous-biphasic hydroformylation of higher alkenes (> C-5) can be greatly accelerated by addition of 1-octyl-3-methylimidazolium bromide without affecting the phase separation and with good catalyst retention in the aqueous phase.

AB - Aqueous-biphasic hydroformylation of higher alkenes (> C-5) can be greatly accelerated by addition of 1-octyl-3-methylimidazolium bromide without affecting the phase separation and with good catalyst retention in the aqueous phase.

KW - SOLUBLE RHODIUM COMPLEX

KW - CATALYZED HYDROFORMYLATION

KW - OLEFIN HYDROFORMYLATION

KW - CYCLODEXTRINS

UR - https://www.scopus.com/pages/publications/34250820574

UR - http://www.rsc.org/Publishing/Journals/CC/article.asp?doi=b618785d

U2 - 10.1039/b618785d

DO - 10.1039/b618785d

M3 - Article

SN - 1359-7345

VL - 2007

SP - 1933

EP - 1935

JO - Chemical Communications

JF - Chemical Communications

IS - 19

ER -

Aqueous-biphasic hydroformylation of higher alkenes promoted by alkylimidazolium salts

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Keywords

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