Application of palladium (trioxo-adamantyl cage phosphine)chloride complexes as catalysts for the alkoxycarbonylation of styrene; Pd catalysed tert-butoxycarbonylation of styrene

José Antonio Fuentes García; Alexandra M. Z. Slawin; Matthew L. Clarke

doi:10.1039/c2cy00521b

Application of palladium (trioxo-adamantyl cage phosphine)chloride complexes as catalysts for the alkoxycarbonylation of styrene; Pd catalysed tert-butoxycarbonylation of styrene

José Antonio Fuentes García, Alexandra M. Z. Slawin, Matthew L. Clarke

Research output: Contribution to journal › Article › peer-review

Abstract

Pre-catalysts of type [PdCl(allyl)(monophosphine)] where the monophosphine is one of the tri-oxo-adamantyl cage phosphines such as 1,3,5,7-tetramethyl-6-phenyl-2,4,8-trioxo-6-phospha-adamantane give very high reactivity in the regioselective hydroxy-carbonylation and alkoxycarbonylation (hydro-esterification) of styrene at 60 degrees C. This high reactivity enables the use of tert-butanol as nucleophile in the alkoxycarbonylation of styrene.

Original language	English
Pages (from-to)	715-718
Number of pages	4
Journal	Catalysis Science & Technology
Volume	2
Issue number	4
DOIs	https://doi.org/10.1039/c2cy00521b
Publication status	Published - 2012

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@article{77f14f16348b4004ac850920a32eea1a,

title = "Application of palladium (trioxo-adamantyl cage phosphine)chloride complexes as catalysts for the alkoxycarbonylation of styrene; Pd catalysed tert-butoxycarbonylation of styrene",

abstract = "Pre-catalysts of type [PdCl(allyl)(monophosphine)] where the monophosphine is one of the tri-oxo-adamantyl cage phosphines such as 1,3,5,7-tetramethyl-6-phenyl-2,4,8-trioxo-6-phospha-adamantane give very high reactivity in the regioselective hydroxy-carbonylation and alkoxycarbonylation (hydro-esterification) of styrene at 60 degrees C. This high reactivity enables the use of tert-butanol as nucleophile in the alkoxycarbonylation of styrene.",

author = "\{Fuentes Garc{\'i}a\}, \{Jos{\'e} Antonio\} and Slawin, \{Alexandra M. Z.\} and Clarke, \{Matthew L.\}",

year = "2012",

doi = "10.1039/c2cy00521b",

language = "English",

volume = "2",

pages = "715--718",

journal = "Catalysis Science \& Technology",

issn = "2044-4753",

publisher = "Royal Society of Chemistry",

number = "4",

}

Application of palladium (trioxo-adamantyl cage phosphine)chloride complexes as catalysts for the alkoxycarbonylation of styrene; Pd catalysed tert-butoxycarbonylation of styrene. / Fuentes García, José Antonio; Slawin, Alexandra M. Z.; Clarke, Matthew L.
In: Catalysis Science & Technology, Vol. 2, No. 4, 2012, p. 715-718.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Application of palladium (trioxo-adamantyl cage phosphine)chloride complexes as catalysts for the alkoxycarbonylation of styrene; Pd catalysed tert-butoxycarbonylation of styrene

AU - Fuentes García, José Antonio

AU - Slawin, Alexandra M. Z.

AU - Clarke, Matthew L.

PY - 2012

Y1 - 2012

N2 - Pre-catalysts of type [PdCl(allyl)(monophosphine)] where the monophosphine is one of the tri-oxo-adamantyl cage phosphines such as 1,3,5,7-tetramethyl-6-phenyl-2,4,8-trioxo-6-phospha-adamantane give very high reactivity in the regioselective hydroxy-carbonylation and alkoxycarbonylation (hydro-esterification) of styrene at 60 degrees C. This high reactivity enables the use of tert-butanol as nucleophile in the alkoxycarbonylation of styrene.

AB - Pre-catalysts of type [PdCl(allyl)(monophosphine)] where the monophosphine is one of the tri-oxo-adamantyl cage phosphines such as 1,3,5,7-tetramethyl-6-phenyl-2,4,8-trioxo-6-phospha-adamantane give very high reactivity in the regioselective hydroxy-carbonylation and alkoxycarbonylation (hydro-esterification) of styrene at 60 degrees C. This high reactivity enables the use of tert-butanol as nucleophile in the alkoxycarbonylation of styrene.

UR - https://www.scopus.com/pages/publications/84859319263

U2 - 10.1039/c2cy00521b

DO - 10.1039/c2cy00521b

M3 - Article

SN - 2044-4753

VL - 2

SP - 715

EP - 718

JO - Catalysis Science & Technology

JF - Catalysis Science & Technology

IS - 4

ER -

Application of palladium (trioxo-adamantyl cage phosphine)chloride complexes as catalysts for the alkoxycarbonylation of styrene; Pd catalysed tert-butoxycarbonylation of styrene

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Self assembly of asymmetric catalysts: Self-assembly of asymmetric catalysts

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Application of palladium (trioxo-adamantyl cage phosphine)chloride complexes as catalysts for the alkoxycarbonylation of styrene; Pd catalysed tert-butoxycarbonylation of styrene

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Self assembly of asymmetric catalysts: Self-assembly of asymmetric catalysts

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