TY - JOUR
T1 - An ionic Cd/Hg mixed-metal complex with an aminoalcohol ligand
AU - Mardani, Zahra
AU - Kazemshoar-Duzduzani, Reza
AU - Moeini, Keyvan
AU - Darroudi, Majid
AU - Carpenter-Warren, Cameron
AU - Slawin, Alexandra M.Z.
AU - Derek Woollins, J.
N1 - This study was supported financially by the Iran National Science Foundation (INSF).
PY - 2018/12/19
Y1 - 2018/12/19
N2 - A cadmium-mercury mixed-metal complex of cis-2-((2-((2-hydroxyethyl)amino)ethyl)amino)cyclohexan-1-ol (HEAC), [Cd(HEAC)2][HgI4] (1), was prepared and identified by elemental analysis, FT-IR, 1H NMR spectroscopy, and single-crystal X-ray diffraction. The X-ray analysis revealed an ionic structure for 1 in which the cadmium and mercury atoms have CdN4O2 and HgI4 environments, with distorted octahedral and tetrahedral geometries, respectively. The packing of the components in the crystal of 1 is supported by O-H···I hydrogen bonds, and these interactions lead to the formation of an R44 ${\rm{R}} $ (22) motif.
AB - A cadmium-mercury mixed-metal complex of cis-2-((2-((2-hydroxyethyl)amino)ethyl)amino)cyclohexan-1-ol (HEAC), [Cd(HEAC)2][HgI4] (1), was prepared and identified by elemental analysis, FT-IR, 1H NMR spectroscopy, and single-crystal X-ray diffraction. The X-ray analysis revealed an ionic structure for 1 in which the cadmium and mercury atoms have CdN4O2 and HgI4 environments, with distorted octahedral and tetrahedral geometries, respectively. The packing of the components in the crystal of 1 is supported by O-H···I hydrogen bonds, and these interactions lead to the formation of an R44 ${\rm{R}} $ (22) motif.
KW - Cd/Hg mixed-metal complex
KW - diastereomer
KW - X-ray crystal structure
KW - β-amino alcohol
U2 - 10.1515/znb-2018-0158
DO - 10.1515/znb-2018-0158
M3 - Article
AN - SCOPUS:85056526552
SN - 0932-0776
VL - 73
SP - 959
EP - 963
JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
JF - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
IS - 12
ER -