An interstitial pyrochlore formed by chemical intercalation of oxygen

J B Thomson, A R Armstrong, P G Bruce

Research output: Contribution to journalArticlepeer-review

18 Citations (Scopus)

Abstract

Oxygen is intercalated, using a solution-based route at ambient temperature, into a pyrochlore oxide, thus establishing a new class of pyrochlore-based interstitial solid solutions: the specific system studied is Ce2Zr2O7 and compositions in the range Ce2Zr2O7+x, 0 < x < 0.36 are obtained; the structure of the most oxygen rich composition has been elucidated by powder neutron diffraction.

Original languageEnglish
Pages (from-to)1165-1166
Number of pages2
JournalChemical Communications
Issue number10
Publication statusPublished - 21 May 1996

Keywords

  • OXIDATION

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