An interstitial pyrochlore formed by chemical intercalation of oxygen

J B  Thomson; A R  Armstrong; P G  Bruce

An interstitial pyrochlore formed by chemical intercalation of oxygen

J B Thomson, A R Armstrong, P G Bruce

Research output: Contribution to journal › Article › peer-review

Abstract

Oxygen is intercalated, using a solution-based route at ambient temperature, into a pyrochlore oxide, thus establishing a new class of pyrochlore-based interstitial solid solutions: the specific system studied is Ce2Zr2O7 and compositions in the range Ce2Zr2O7+x, 0 < x < 0.36 are obtained; the structure of the most oxygen rich composition has been elucidated by powder neutron diffraction.

Original language	English
Pages (from-to)	1165-1166
Number of pages	2
Journal	Chemical Communications
Issue number	10
Publication status	Published - 21 May 1996

Keywords

OXIDATION

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title = "An interstitial pyrochlore formed by chemical intercalation of oxygen",

abstract = "Oxygen is intercalated, using a solution-based route at ambient temperature, into a pyrochlore oxide, thus establishing a new class of pyrochlore-based interstitial solid solutions: the specific system studied is Ce2Zr2O7 and compositions in the range Ce2Zr2O7+x, 0 < x < 0.36 are obtained; the structure of the most oxygen rich composition has been elucidated by powder neutron diffraction.",

keywords = "OXIDATION",

author = "Thomson, {J B} and Armstrong, {A R} and Bruce, {P G}",

year = "1996",

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day = "21",

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journal = "Chemical Communications",

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T1 - An interstitial pyrochlore formed by chemical intercalation of oxygen

AU - Thomson, J B

AU - Armstrong, A R

AU - Bruce, P G

PY - 1996/5/21

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N2 - Oxygen is intercalated, using a solution-based route at ambient temperature, into a pyrochlore oxide, thus establishing a new class of pyrochlore-based interstitial solid solutions: the specific system studied is Ce2Zr2O7 and compositions in the range Ce2Zr2O7+x, 0 < x < 0.36 are obtained; the structure of the most oxygen rich composition has been elucidated by powder neutron diffraction.

AB - Oxygen is intercalated, using a solution-based route at ambient temperature, into a pyrochlore oxide, thus establishing a new class of pyrochlore-based interstitial solid solutions: the specific system studied is Ce2Zr2O7 and compositions in the range Ce2Zr2O7+x, 0 < x < 0.36 are obtained; the structure of the most oxygen rich composition has been elucidated by powder neutron diffraction.

KW - OXIDATION

M3 - Article

SN - 1359-7345

SP - 1165

EP - 1166

JO - Chemical Communications

JF - Chemical Communications

IS - 10

ER -

An interstitial pyrochlore formed by chemical intercalation of oxygen

Abstract

Keywords

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