An expanded MIL-53-type coordination polymer with a reactive pendant ligand

Hannah Kunicki; Thomas Chamberlain; Guy Clarkson; Reza Kashtiban; Joseph E. Hooper; Daniel M. Dawson; Sharon E. Ashbrook; Richard Walton

doi:10.1039/C8CE00891D

An expanded MIL-53-type coordination polymer with a reactive pendant ligand

Hannah Kunicki, Thomas Chamberlain, Guy Clarkson, Reza Kashtiban, Joseph E. Hooper, Daniel M. Dawson, Sharon E. Ashbrook, Richard Walton

Research output: Contribution to journal › Article › peer-review

Abstract

A coordination polymer with a structure isoreticular to MIL-53, but containing a divalent metal cation (Co²⁺ or Mg²⁺⁾ and a coordinating 4-styrylpyridine-N-oxide ligand, crystallises under solvothermal conditions; the pendant ligand can be brominated, with evidence from powder X-ray diffraction, element mapping and ⁸¹Br solid- state NMR for this post-synthesis modification.

Original language	English
Number of pages	4
Journal	CrystEngComm
Volume	Advance Article
Early online date	18 Jul 2018
DOIs	https://doi.org/10.1039/C8CE00891D
Publication status	E-pub ahead of print - 18 Jul 2018

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Kunicki_2018_CrystEngComm_MIL-53_CC
© 2018 The Author(s). Open Access Article. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Final published version, 1.42 MBLicence: CC BY

EXONMR: EU FP7 Consolidator 2013 EXONMR
Ashbrook, S. E. (PI)
European Research Council
1/04/14 → 30/09/19
Project: Standard

An expanded MIL-53-type coordination polymer with a reactive pendant ligand (crystallography data)
Kunicki, H. (Creator), Chamberlain, T. (Creator), Clarkson, G. (Creator), Kashtiban, R. (Creator), Hooper, J. E. (Creator), Dawson, D. M. (Creator), Ashbrook, S. E. M. (Creator) & v, R. (Creator), Cambridge Crystallographic Data Centre, 8 May 2018
https://dx.doi.org/10.5517/ccdc.csd.cc1ztxd3 and 2 more links, https://dx.doi.org/10.5517/ccdc.csd.cc1ztxg5, https://dx.doi.org/10.5517/ccdc.csd.cc1ztxf4 (show fewer)
Dataset
Data for An expanded MIL-53-type coordination polymer with a reactive pendant ligand
Kunicki, H. (Creator), Chamberlain, T. W. (Creator), Clarkson, G. J. (Creator), Kashtiban, R. J. (Creator), Hooper, J. E. (Creator), Dawson, D. M. (Creator), Ashbrook, S. E. M. (Creator) & Walton, R. I. (Creator), University of Warwick Publications service & WRAP, 3 Jul 2018
Dataset

Cite this

@article{f726367e923b49bd9a13ed7f21702a73,

title = "An expanded MIL-53-type coordination polymer with a reactive pendant ligand",

abstract = "A coordination polymer with a structure isoreticular to MIL-53, but containing a divalent metal cation (Co2+ or Mg2+) and a coordinating 4-styrylpyridine-N-oxide ligand, crystallises under solvothermal conditions; the pendant ligand can be brominated, with evidence from powder X-ray diffraction, element mapping and 81Br solid- state NMR for this post-synthesis modification.",

author = "Hannah Kunicki and Thomas Chamberlain and Guy Clarkson and Reza Kashtiban and Hooper, {Joseph E.} and Dawson, {Daniel M.} and Ashbrook, {Sharon E.} and Richard Walton",

note = "The authors acknowledge the University of Warwick Undergraduate Research Support Scheme for award of a bursary to TWC. The EPSRC{\textquoteright}s UK National Crystallography Service at the University of Southampton is thanked for one of the data sets. The UK 850 MHz solid-state NMR Facility was funded by EPSRC and BBSRC (contract reference PR140003), as well as the University of Warwick including via part funding through Birmingham Science City Advanced Materials Projects 1 and 2 supported by Advantage West Midlands (AWM) and the European Regional Development Fund (ERDF). SEA would like to thank the ERC (EU FP7 Consolidator Grant 614290 “EXONMR”).",

year = "2018",

month = jul,

day = "18",

doi = "10.1039/C8CE00891D",

language = "English",

volume = "Advance Article",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "ROYAL SOC CHEMISTRY",

}

TY - JOUR

T1 - An expanded MIL-53-type coordination polymer with a reactive pendant ligand

AU - Kunicki, Hannah

AU - Chamberlain, Thomas

AU - Clarkson, Guy

AU - Kashtiban, Reza

AU - Hooper, Joseph E.

AU - Dawson, Daniel M.

AU - Ashbrook, Sharon E.

AU - Walton, Richard

N1 - The authors acknowledge the University of Warwick Undergraduate Research Support Scheme for award of a bursary to TWC. The EPSRC’s UK National Crystallography Service at the University of Southampton is thanked for one of the data sets. The UK 850 MHz solid-state NMR Facility was funded by EPSRC and BBSRC (contract reference PR140003), as well as the University of Warwick including via part funding through Birmingham Science City Advanced Materials Projects 1 and 2 supported by Advantage West Midlands (AWM) and the European Regional Development Fund (ERDF). SEA would like to thank the ERC (EU FP7 Consolidator Grant 614290 “EXONMR”).

PY - 2018/7/18

Y1 - 2018/7/18

N2 - A coordination polymer with a structure isoreticular to MIL-53, but containing a divalent metal cation (Co2+ or Mg2+) and a coordinating 4-styrylpyridine-N-oxide ligand, crystallises under solvothermal conditions; the pendant ligand can be brominated, with evidence from powder X-ray diffraction, element mapping and 81Br solid- state NMR for this post-synthesis modification.

AB - A coordination polymer with a structure isoreticular to MIL-53, but containing a divalent metal cation (Co2+ or Mg2+) and a coordinating 4-styrylpyridine-N-oxide ligand, crystallises under solvothermal conditions; the pendant ligand can be brominated, with evidence from powder X-ray diffraction, element mapping and 81Br solid- state NMR for this post-synthesis modification.

U2 - 10.1039/C8CE00891D

DO - 10.1039/C8CE00891D

M3 - Article

SN - 1466-8033

VL - Advance Article

JO - CrystEngComm

JF - CrystEngComm

ER -

An expanded MIL-53-type coordination polymer with a reactive pendant ligand

Abstract

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EXONMR: EU FP7 Consolidator 2013 EXONMR

Datasets

An expanded MIL-53-type coordination polymer with a reactive pendant ligand (crystallography data)

Data for An expanded MIL-53-type coordination polymer with a reactive pendant ligand

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