An expanded MIL-53-type coordination polymer with a reactive pendant ligand

Hannah Kunicki, Thomas Chamberlain, Guy Clarkson, Reza Kashtiban, Joseph E. Hooper, Daniel M. Dawson, Sharon E. Ashbrook, Richard Walton

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)
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Abstract

A coordination polymer with a structure isoreticular to MIL-53, but containing a divalent metal cation (Co2+ or Mg2+) and a coordinating 4-styrylpyridine-N-oxide ligand, crystallises under solvothermal conditions; the pendant ligand can be brominated, with evidence from powder X-ray diffraction, element mapping and 81Br solid- state NMR for this post-synthesis modification.
Original languageEnglish
Number of pages4
JournalCrystEngComm
VolumeAdvance Article
Early online date18 Jul 2018
DOIs
Publication statusE-pub ahead of print - 18 Jul 2018

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