An E.S.R. study of bicyclo[1.1.1]pent-1-yl radicals

Bernard Maillard; John C. Walton

doi:10.1039/c39830000900

An E.S.R. study of bicyclo[1.1.1]pent-1-yl radicals

Bernard Maillard^*, John C. Walton

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The e.s.r. spectrum of bicyclo[1.1.1]pent-1-yl radicals shows a very large hyperfine splitting from the bridgehead γ-hydrogen; this is probably due to the through space and through bond orbital interactions reinforcing one another.

Original language	English
Pages (from-to)	900-901
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/c39830000900
Publication status	Published - 1 Jan 1983

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title = "An E.S.R. study of bicyclo[1.1.1]pent-1-yl radicals",

abstract = "The e.s.r. spectrum of bicyclo[1.1.1]pent-1-yl radicals shows a very large hyperfine splitting from the bridgehead γ-hydrogen; this is probably due to the through space and through bond orbital interactions reinforcing one another.",

author = "Bernard Maillard and Walton, \{John C.\}",

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AB - The e.s.r. spectrum of bicyclo[1.1.1]pent-1-yl radicals shows a very large hyperfine splitting from the bridgehead γ-hydrogen; this is probably due to the through space and through bond orbital interactions reinforcing one another.

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JF - Journal of the Chemical Society, Chemical Communications

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An E.S.R. study of bicyclo[1.1.1]pent-1-yl radicals

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