An efficient, scalable synthesis of ferrocenylphosphine and dichloroferrocenylphosphine

Brian Andrew Surgenor; Laurence John Taylor; Andreas Nordheider; Alexandra Martha Zoya Slawin; Kasun Sankalpa Athukorala Arachchige; John Derek Woollins; Petr Kilian

doi:10.1039/C5RA27594F

An efficient, scalable synthesis of ferrocenylphosphine and dichloroferrocenylphosphine

Brian Andrew Surgenor, Laurence John Taylor, Andreas Nordheider, Alexandra Martha Zoya Slawin, Kasun Sankalpa Athukorala Arachchige, John Derek Woollins, Petr Kilian

Research output: Contribution to journal › Article › peer-review

Abstract

A new synthetic route to FcPH₂ and FcPCl₂ (Fc = Ferrocenyl) is presented. This method avoids the challenging monolithiation of ferrocene, as well as any tedious purification steps. All reactions are high yielding and easily conducted on a relatively large scale, using economical and commercially available synthetic precursors.

Original language	English
Pages (from-to)	5973-5976
Journal	RSC Advances
Volume	7
Early online date	8 Jan 2016
DOIs	https://doi.org/10.1039/C5RA27594F
Publication status	Published - 2016

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10.1039/C5RA27594F

Kilian_2016_RSCA_EfficienctScalable_AM
Copyright 2016 the Authors. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at: https://dx.doi.org/10.1039/C5RA27594F
Accepted author manuscript, 466 KB
Kilian_2016_RSCA_EfficienctScalable_Supplement_AM
Copyright 2016 the Authors. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at: https://dx.doi.org/10.1039/C5RA27594F
Accepted author manuscript, 455 KB

An efficient, scalable synthesis of ferrocenylphosphine and dichloroferrocenylphosphine (dataset)
Surgenor, B. A. (Creator), Taylor, L. J. (Creator), Nordheider, A. (Creator), Slawin, A. M. Z. (Creator), Athukorala Arachchige, K. S. (Creator), Woollins, J. D. (Creator) & Kilian, P. (Creator), Cambridge Crystallographic Data Centre, 2016
https://dx.doi.org/10.5517/ccw88p2 and one more link, https://dx.doi.org/10.5517/cc1k7llz (show fewer)
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@article{edb95df99f5c44c1a44cfb1b142321d2,

title = "An efficient, scalable synthesis of ferrocenylphosphine and dichloroferrocenylphosphine",

abstract = "A new synthetic route to FcPH2 and FcPCl2 (Fc = Ferrocenyl) is presented. This method avoids the challenging monolithiation of ferrocene, as well as any tedious purification steps. All reactions are high yielding and easily conducted on a relatively large scale, using economical and commercially available synthetic precursors.",

author = "Surgenor, {Brian Andrew} and Taylor, {Laurence John} and Andreas Nordheider and Slawin, {Alexandra Martha Zoya} and {Athukorala Arachchige}, {Kasun Sankalpa} and Woollins, {John Derek} and Petr Kilian",

note = "This work was financially supported by the Engineering and Physical Sciences Research Council (EPSRC) and by COST action (grant CM1302, SIPs).",

year = "2016",

doi = "10.1039/C5RA27594F",

language = "English",

volume = "7",

pages = "5973--5976",

journal = "RSC Advances",

issn = "2046-2069",

publisher = "Royal Society of Chemistry",

}

TY - JOUR

T1 - An efficient, scalable synthesis of ferrocenylphosphine and dichloroferrocenylphosphine

AU - Surgenor, Brian Andrew

AU - Taylor, Laurence John

AU - Nordheider, Andreas

AU - Slawin, Alexandra Martha Zoya

AU - Athukorala Arachchige, Kasun Sankalpa

AU - Woollins, John Derek

AU - Kilian, Petr

N1 - This work was financially supported by the Engineering and Physical Sciences Research Council (EPSRC) and by COST action (grant CM1302, SIPs).

PY - 2016

Y1 - 2016

N2 - A new synthetic route to FcPH2 and FcPCl2 (Fc = Ferrocenyl) is presented. This method avoids the challenging monolithiation of ferrocene, as well as any tedious purification steps. All reactions are high yielding and easily conducted on a relatively large scale, using economical and commercially available synthetic precursors.

AB - A new synthetic route to FcPH2 and FcPCl2 (Fc = Ferrocenyl) is presented. This method avoids the challenging monolithiation of ferrocene, as well as any tedious purification steps. All reactions are high yielding and easily conducted on a relatively large scale, using economical and commercially available synthetic precursors.

U2 - 10.1039/C5RA27594F

DO - 10.1039/C5RA27594F

M3 - Article

SN - 2046-2069

VL - 7

SP - 5973

EP - 5976

JO - RSC Advances

JF - RSC Advances

ER -

An efficient, scalable synthesis of ferrocenylphosphine and dichloroferrocenylphosphine

Abstract

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An efficient, scalable synthesis of ferrocenylphosphine and dichloroferrocenylphosphine (dataset)

Cite this