An efficient route for the synthesis of phosphorus-selenium macro-heterocycles

Guoxiong Hua; Alexandra M. Z. Slawin; Rebecca A. M. Randall; David B. Cordes; Luke Crawford; Michael Buehl; J. Derek Woollins

doi:10.1039/c3cc40515j

An efficient route for the synthesis of phosphorus-selenium macro-heterocycles

Guoxiong Hua, Alexandra M. Z. Slawin, Rebecca A. M. Randall, David B. Cordes, Luke Crawford, Michael Buehl, J. Derek Woollins^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

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Abstract

Four-membered ring [PhP(Se)(mu-Se)](2) (Woollins' reagent, WR) reacts with disodium alkenyl-diols followed by in situ ring-closure reaction with appropriate dibromoalkanes affording a series of unusual nine-to fifteen-membered organoselenophosphorus macrocycles bearing the O-P-Se-C-n-Se-P-O or O-P-Se-C-n-O-P-Se linkage.

Original language	English
Pages (from-to)	2619-2621
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	26
Early online date	13 Feb 2013
DOIs	https://doi.org/10.1039/c3cc40515j
Publication status	Published - Apr 2013

Keywords

P-SE Heterocycles
Atoms
Rings
Woollins reagent

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10.1039/c3cc40515j

Woollins2013ChemComm49 26c3cc40515j
This is an open access article. This journal is © The Royal Society of Chemistry 2013
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title = "An efficient route for the synthesis of phosphorus-selenium macro-heterocycles",

abstract = "Four-membered ring [PhP(Se)(mu-Se)](2) (Woollins' reagent, WR) reacts with disodium alkenyl-diols followed by in situ ring-closure reaction with appropriate dibromoalkanes affording a series of unusual nine-to fifteen-membered organoselenophosphorus macrocycles bearing the O-P-Se-C-n-Se-P-O or O-P-Se-C-n-O-P-Se linkage.",

keywords = "P-SE Heterocycles, Atoms, Rings, Woollins reagent",

author = "Guoxiong Hua and Slawin, {Alexandra M. Z.} and Randall, {Rebecca A. M.} and Cordes, {David B.} and Luke Crawford and Michael Buehl and Woollins, {J. Derek}",

year = "2013",

month = apr,

doi = "10.1039/c3cc40515j",

language = "English",

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pages = "2619--2621",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - An efficient route for the synthesis of phosphorus-selenium macro-heterocycles

AU - Hua, Guoxiong

AU - Slawin, Alexandra M. Z.

AU - Randall, Rebecca A. M.

AU - Cordes, David B.

AU - Crawford, Luke

AU - Buehl, Michael

AU - Woollins, J. Derek

PY - 2013/4

Y1 - 2013/4

N2 - Four-membered ring [PhP(Se)(mu-Se)](2) (Woollins' reagent, WR) reacts with disodium alkenyl-diols followed by in situ ring-closure reaction with appropriate dibromoalkanes affording a series of unusual nine-to fifteen-membered organoselenophosphorus macrocycles bearing the O-P-Se-C-n-Se-P-O or O-P-Se-C-n-O-P-Se linkage.

AB - Four-membered ring [PhP(Se)(mu-Se)](2) (Woollins' reagent, WR) reacts with disodium alkenyl-diols followed by in situ ring-closure reaction with appropriate dibromoalkanes affording a series of unusual nine-to fifteen-membered organoselenophosphorus macrocycles bearing the O-P-Se-C-n-Se-P-O or O-P-Se-C-n-O-P-Se linkage.

KW - P-SE Heterocycles

KW - Atoms

KW - Rings

KW - Woollins reagent

U2 - 10.1039/c3cc40515j

DO - 10.1039/c3cc40515j

M3 - Article

SN - 1359-7345

VL - 49

SP - 2619

EP - 2621

JO - Chemical Communications

JF - Chemical Communications

IS - 26

ER -

An efficient route for the synthesis of phosphorus-selenium macro-heterocycles

Abstract

Keywords

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