An Efficient Palladium-NHC (NHC=N-Heterocyclic Carbene) and Aryl Amination Pre-Catalyst: [Pd(IPr*)(cinnamyl)Cl]

Anthony Chartoire; Xavier Frogneux; Steven P. Nolan

doi:10.1002/adsc.201200207

An Efficient Palladium-NHC (NHC=N-Heterocyclic Carbene) and Aryl Amination Pre-Catalyst: [Pd(IPr*)(cinnamyl)Cl]

Anthony Chartoire, Xavier Frogneux, Steven P. Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

The well-defined [Pd(IPr*)(cinnamyl)Cl] complex is reported as one of the best N-heterocyclic carbene (NHC)-based pre-catalysts for the BuchwaldHartwig amination reaction. This catalytic system displays high efficiency for the coupling of numerous (hetero)aryl chlorides, with a wide range of amines, at room temperature or at extremely low catalyst loading (as low as 0.025 mol%).

Original language	English
Pages (from-to)	1897-1901
Number of pages	5
Journal	Advanced Synthesis & Catalysis
Volume	354
Issue number	10
DOIs	https://doi.org/10.1002/adsc.201200207
Publication status	Published - Jul 2012

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abstract = "The well-defined [Pd(IPr*)(cinnamyl)Cl] complex is reported as one of the best N-heterocyclic carbene (NHC)-based pre-catalysts for the BuchwaldHartwig amination reaction. This catalytic system displays high efficiency for the coupling of numerous (hetero)aryl chlorides, with a wide range of amines, at room temperature or at extremely low catalyst loading (as low as 0.025 mol\%).",

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AU - Nolan, Steven P.

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AB - The well-defined [Pd(IPr*)(cinnamyl)Cl] complex is reported as one of the best N-heterocyclic carbene (NHC)-based pre-catalysts for the BuchwaldHartwig amination reaction. This catalytic system displays high efficiency for the coupling of numerous (hetero)aryl chlorides, with a wide range of amines, at room temperature or at extremely low catalyst loading (as low as 0.025 mol%).

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An Efficient Palladium-NHC (NHC=N-Heterocyclic Carbene) and Aryl Amination Pre-Catalyst: [Pd(IPr*)(cinnamyl)Cl]

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