An Asymmetric Hydroformylation Catalyst that Delivers Branched Aldehydes from Alkyl Alkenes

Gary M Noonan; José Antonio Fuentes García; Christopher J. Cobley; Matthew L. Clarke

doi:10.1002/anie.201108203

An Asymmetric Hydroformylation Catalyst that Delivers Branched Aldehydes from Alkyl Alkenes

Gary M Noonan, José Antonio Fuentes García, Christopher J. Cobley, Matthew L. Clarke

Research output: Contribution to journal › Article › peer-review

Abstract

Surprising selectivity: The first enantioselective hydroformylations of simple alkenes of type RCH2CH=CH2 to preferentially deliver the branched aldehyde product have been discovered using a new chiral ligand, named bobphos (see scheme). Established ligands are unselective in this reaction or show a slight preference towards the linear aldehyde.

Original language	English
Pages (from-to)	2477-2480
Number of pages	4
Journal	Angewandte Chemie International Edition
Volume	51
Issue number	10
DOIs	https://doi.org/10.1002/anie.201108203
Publication status	Published - 5 Mar 2012

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title = "An Asymmetric Hydroformylation Catalyst that Delivers Branched Aldehydes from Alkyl Alkenes",

abstract = "Surprising selectivity: The first enantioselective hydroformylations of simple alkenes of type RCH2CH=CH2 to preferentially deliver the branched aldehyde product have been discovered using a new chiral ligand, named bobphos (see scheme). Established ligands are unselective in this reaction or show a slight preference towards the linear aldehyde.",

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AU - Clarke, Matthew L.

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AB - Surprising selectivity: The first enantioselective hydroformylations of simple alkenes of type RCH2CH=CH2 to preferentially deliver the branched aldehyde product have been discovered using a new chiral ligand, named bobphos (see scheme). Established ligands are unselective in this reaction or show a slight preference towards the linear aldehyde.

UR - https://www.scopus.com/pages/publications/84857938093

U2 - 10.1002/anie.201108203

DO - 10.1002/anie.201108203

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JF - Angewandte Chemie International Edition

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An Asymmetric Hydroformylation Catalyst that Delivers Branched Aldehydes from Alkyl Alkenes

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