An Asymmetric Hydroformylation Catalyst that Delivers Branched Aldehydes from Alkyl Alkenes

Gary M Noonan; José Antonio Fuentes García; Christopher J. Cobley; Matthew L. Clarke

doi:10.1002/anie.201108203

An Asymmetric Hydroformylation Catalyst that Delivers Branched Aldehydes from Alkyl Alkenes

Gary M Noonan, José Antonio Fuentes García, Christopher J. Cobley, Matthew L. Clarke

Research output: Contribution to journal › Article › peer-review

Abstract

Surprising selectivity: The first enantioselective hydroformylations of simple alkenes of type RCH2CH=CH2 to preferentially deliver the branched aldehyde product have been discovered using a new chiral ligand, named bobphos (see scheme). Established ligands are unselective in this reaction or show a slight preference towards the linear aldehyde.

Original language	English
Pages (from-to)	2477-2480
Number of pages	4
Journal	Angewandte Chemie International Edition
Volume	51
Issue number	10
DOIs	https://doi.org/10.1002/anie.201108203
Publication status	Published - 5 Mar 2012

Access to Document

10.1002/anie.201108203

Cite this

@article{698c76805d2041c7b8a89476680d6105,

title = "An Asymmetric Hydroformylation Catalyst that Delivers Branched Aldehydes from Alkyl Alkenes",

abstract = "Surprising selectivity: The first enantioselective hydroformylations of simple alkenes of type RCH2CH=CH2 to preferentially deliver the branched aldehyde product have been discovered using a new chiral ligand, named bobphos (see scheme). Established ligands are unselective in this reaction or show a slight preference towards the linear aldehyde.",

author = "Noonan, {Gary M} and {Fuentes Garc{\'i}a}, {Jos{\'e} Antonio} and Cobley, {Christopher J.} and Clarke, {Matthew L.}",

year = "2012",

month = mar,

day = "5",

doi = "10.1002/anie.201108203",

language = "English",

volume = "51",

pages = "2477--2480",

journal = "Angewandte Chemie International Edition",

issn = "1433-7851",

publisher = "John Wiley & Sons, Ltd",

number = "10",

}

TY - JOUR

T1 - An Asymmetric Hydroformylation Catalyst that Delivers Branched Aldehydes from Alkyl Alkenes

AU - Noonan, Gary M

AU - Fuentes García, José Antonio

AU - Cobley, Christopher J.

AU - Clarke, Matthew L.

PY - 2012/3/5

Y1 - 2012/3/5

N2 - Surprising selectivity: The first enantioselective hydroformylations of simple alkenes of type RCH2CH=CH2 to preferentially deliver the branched aldehyde product have been discovered using a new chiral ligand, named bobphos (see scheme). Established ligands are unselective in this reaction or show a slight preference towards the linear aldehyde.

AB - Surprising selectivity: The first enantioselective hydroformylations of simple alkenes of type RCH2CH=CH2 to preferentially deliver the branched aldehyde product have been discovered using a new chiral ligand, named bobphos (see scheme). Established ligands are unselective in this reaction or show a slight preference towards the linear aldehyde.

U2 - 10.1002/anie.201108203

DO - 10.1002/anie.201108203

M3 - Article

SN - 1433-7851

VL - 51

SP - 2477

EP - 2480

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 10

ER -

An Asymmetric Hydroformylation Catalyst that Delivers Branched Aldehydes from Alkyl Alkenes

Abstract

Access to Document

Fingerprint

Cite this