Ammonium scandium tetrafluoride

Nicholas F. Stephens, Philip Lightfoot

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

The title compound, NH4ScF4, is an addition to the AMF(4) family of layered perovskite-like structures. The structure consists of a two-dimensional array of corner-sharing ScF6 octahedra, which produces anionic sheets of stoichiometry [ScF4]. stacked along the c axis. The layers are separated by charge-balancing ammonium cations, which hydrogen bond to the apical F atoms of adjacent layers. This structure may be viewed as a 'single-layer' fluoride analogue of the Dion-Jacobson family of oxides.

Original languageEnglish
Number of pages3
JournalActa Crystallographica Section C-Crystal Structure Communications
Volume62
DOIs
Publication statusPublished - Dec 2006

Keywords

  • FLUORIDE

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