Amidine catalysed O- to C-carboxyl transfer of heterocyclic carbonate derivatives

Caroline Joannesse, Carmen Simal, Carmen Concellon, Jennifer E. Thomson, Craig D. Campbell, Alexandra M. Z. Slawin, Andrew D. Smith

Research output: Contribution to journalArticlepeer-review

39 Citations (Scopus)

Abstract

The structural requirements of amidines necessary to act as efficient O- to C-carboxyl transfer agents are delineated and the scope of this process outlined through its application to a range of oxazolyl, benzofuranyl and indolyl carbonates.

Original languageEnglish
Pages (from-to)2900-2907
Number of pages8
JournalOrganic & Biomolecular Chemistry
Volume6
DOIs
Publication statusPublished - 21 Aug 2008

Keywords

  • ACYL TRANSFER CATALYST
  • KINETIC RESOLUTION
  • NUCLEOPHILIC CATALYSIS
  • ACYLATION CATALYSTS
  • QUATERNARY CARBON
  • ALCOHOLS
  • DBU
  • MIGRATION
  • BENZOTETRAMISOLE
  • BENZOFURANONES

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