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Abstract
alpha-Aroyloxyaldehydes are readily prepared bench stable synthetic intermediates. Their ability to act as alpha-haloaldehyde surrogates for NHC-promoted redox esterifications and in [4+2] cycloadditions is described.
Original language | English |
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Pages (from-to) | 373-375 |
Number of pages | 3 |
Journal | Chemical Communications |
Volume | 47 |
Issue number | 1 |
DOIs | |
Publication status | Published - 2011 |
Keywords
- N-HETEROCYCLIC CARBENES
- DIELS-ALDER REACTIONS
- RING EXPANSION
- ALPHA,BETA-UNSATURATED ALDEHYDES
- STEREOSELECTIVE-SYNTHESIS
- ACTIVATED CARBOXYLATES
- NUCLEOPHILIC CARBENES
- ESTERS
- OXIDATION
- GENERATION
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Dive into the research topics of 'alpha-Aroyloxyaldehydes: scope and limitations as alternatives to alpha-haloaldehydes for NHC-catalysed redox transformations'. Together they form a unique fingerprint.Projects
- 1 Finished
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N-Heterocyclic Carbenes as Asymmetric: N-Heterocyclic Carbenes as Asymmetric Organocatalysts: Reaction Development
Smith, A. D. (PI)
1/04/07 → 30/09/10
Project: Standard