Adducts between silver nitrate and di-iodo compounds, and some analogues

H. N. Aliyu; R. D. Gillard; J. D. Honeywill; P. Lightfoot; J. Rocha

doi:10.1016/0277-5387(95)00508-0

Adducts between silver nitrate and di-iodo compounds, and some analogues

H. N. Aliyu, R. D. Gillard^*, J. D. Honeywill, P. Lightfoot, J. Rocha

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction under defined conditions between aqueous silver nitrate and di-iodoalkanes with adjacent iodine atoms, such as CH₂I₂, CHI₃, C₂I₄ or with di-iodobenzenes (1,2-; 1,4-) may give 1 : 1 solid adducts. Vibrational spectroscopy, solid-state NMR spectra and powder X-ray diffraction show that the organic molecules act as donor ligands. The known inverse compounds [XAg₃](NO₃)₂ (X = Br,I) may also be formed conveniently from reactions of iodo-organic vapours with silver nitrate solutions. Compounds in the homologous series (CH₂)_nI₂ (2 < n < 11) form the inverse compounds [XAg_n](NO₃)_n-1 (n = 2 or 3) with aqueous silver nitrate under all conditions.

Original language	English
Pages (from-to)	2409-2419
Number of pages	11
Journal	Polyhedron
Volume	15
Issue number	14
DOIs	https://doi.org/10.1016/0277-5387(95)00508-0
Publication status	Published - 1 Jan 1996

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title = "Adducts between silver nitrate and di-iodo compounds, and some analogues",

abstract = "Reaction under defined conditions between aqueous silver nitrate and di-iodoalkanes with adjacent iodine atoms, such as CH2I2, CHI3, C2I4 or with di-iodobenzenes (1,2-; 1,4-) may give 1 : 1 solid adducts. Vibrational spectroscopy, solid-state NMR spectra and powder X-ray diffraction show that the organic molecules act as donor ligands. The known inverse compounds [XAg3](NO3)2 (X = Br,I) may also be formed conveniently from reactions of iodo-organic vapours with silver nitrate solutions. Compounds in the homologous series (CH2)nI2 (2 < n < 11) form the inverse compounds [XAgn](NO3)n-1 (n = 2 or 3) with aqueous silver nitrate under all conditions.",

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T1 - Adducts between silver nitrate and di-iodo compounds, and some analogues

AU - Aliyu, H. N.

AU - Gillard, R. D.

AU - Honeywill, J. D.

AU - Lightfoot, P.

AU - Rocha, J.

PY - 1996/1/1

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N2 - Reaction under defined conditions between aqueous silver nitrate and di-iodoalkanes with adjacent iodine atoms, such as CH2I2, CHI3, C2I4 or with di-iodobenzenes (1,2-; 1,4-) may give 1 : 1 solid adducts. Vibrational spectroscopy, solid-state NMR spectra and powder X-ray diffraction show that the organic molecules act as donor ligands. The known inverse compounds [XAg3](NO3)2 (X = Br,I) may also be formed conveniently from reactions of iodo-organic vapours with silver nitrate solutions. Compounds in the homologous series (CH2)nI2 (2 < n < 11) form the inverse compounds [XAgn](NO3)n-1 (n = 2 or 3) with aqueous silver nitrate under all conditions.

AB - Reaction under defined conditions between aqueous silver nitrate and di-iodoalkanes with adjacent iodine atoms, such as CH2I2, CHI3, C2I4 or with di-iodobenzenes (1,2-; 1,4-) may give 1 : 1 solid adducts. Vibrational spectroscopy, solid-state NMR spectra and powder X-ray diffraction show that the organic molecules act as donor ligands. The known inverse compounds [XAg3](NO3)2 (X = Br,I) may also be formed conveniently from reactions of iodo-organic vapours with silver nitrate solutions. Compounds in the homologous series (CH2)nI2 (2 < n < 11) form the inverse compounds [XAgn](NO3)n-1 (n = 2 or 3) with aqueous silver nitrate under all conditions.

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Adducts between silver nitrate and di-iodo compounds, and some analogues

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