ADDITION OF ALKYNES TO (VINYLKETENE)TRICARBONYLIRON(0) COMPLEXES

K G  MORRIS; S P  SABERI; A M Z  SLAWIN; S E  THOMAS; D J  WILLIAMS

ADDITION OF ALKYNES TO (VINYLKETENE)TRICARBONYLIRON(0) COMPLEXES

K G MORRIS, S P SABERI, A M Z SLAWIN, S E THOMAS, D J WILLIAMS

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Abstract

Alkynes add to (vinylketene)tricarbonyliron(0) complexes to generate stable adducts; addition of unsymmetrical alkynes is highly regioselective and the regiochemistries of the adducts produced in these reactions were determined by X-ray crystal structure analyses of the major isomer derived from but-3-yn-2-one and (3-tert-butyl-5-phenyl-1-oxapenta-1,2,4-triene)tricarbonyliron(0), and of the structurally modified product derived from diethylpropynylamine and (3-isopropyl-5-phenyl-1-oxapenta-1,2-4-triene)tricarbonyliron(0).

Original language	English
Pages (from-to)	1788-1791
Number of pages	4
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	24
Publication status	Published - 15 Dec 1992

Keywords

CARBENE

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title = "ADDITION OF ALKYNES TO (VINYLKETENE)TRICARBONYLIRON(0) COMPLEXES",

abstract = "Alkynes add to (vinylketene)tricarbonyliron(0) complexes to generate stable adducts; addition of unsymmetrical alkynes is highly regioselective and the regiochemistries of the adducts produced in these reactions were determined by X-ray crystal structure analyses of the major isomer derived from but-3-yn-2-one and (3-tert-butyl-5-phenyl-1-oxapenta-1,2,4-triene)tricarbonyliron(0), and of the structurally modified product derived from diethylpropynylamine and (3-isopropyl-5-phenyl-1-oxapenta-1,2-4-triene)tricarbonyliron(0).",

keywords = "CARBENE",

author = "MORRIS, {K G} and SABERI, {S P} and SLAWIN, {A M Z} and THOMAS, {S E} and WILLIAMS, {D J}",

year = "1992",

month = dec,

day = "15",

language = "English",

pages = "1788--1791",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "24",

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TY - JOUR

T1 - ADDITION OF ALKYNES TO (VINYLKETENE)TRICARBONYLIRON(0) COMPLEXES

AU - MORRIS, K G

AU - SABERI, S P

AU - SLAWIN, A M Z

AU - THOMAS, S E

AU - WILLIAMS, D J

PY - 1992/12/15

Y1 - 1992/12/15

N2 - Alkynes add to (vinylketene)tricarbonyliron(0) complexes to generate stable adducts; addition of unsymmetrical alkynes is highly regioselective and the regiochemistries of the adducts produced in these reactions were determined by X-ray crystal structure analyses of the major isomer derived from but-3-yn-2-one and (3-tert-butyl-5-phenyl-1-oxapenta-1,2,4-triene)tricarbonyliron(0), and of the structurally modified product derived from diethylpropynylamine and (3-isopropyl-5-phenyl-1-oxapenta-1,2-4-triene)tricarbonyliron(0).

AB - Alkynes add to (vinylketene)tricarbonyliron(0) complexes to generate stable adducts; addition of unsymmetrical alkynes is highly regioselective and the regiochemistries of the adducts produced in these reactions were determined by X-ray crystal structure analyses of the major isomer derived from but-3-yn-2-one and (3-tert-butyl-5-phenyl-1-oxapenta-1,2,4-triene)tricarbonyliron(0), and of the structurally modified product derived from diethylpropynylamine and (3-isopropyl-5-phenyl-1-oxapenta-1,2-4-triene)tricarbonyliron(0).

KW - CARBENE

M3 - Article

SN - 0022-4936

SP - 1788

EP - 1791

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 24

ER -

ADDITION OF ALKYNES TO (VINYLKETENE)TRICARBONYLIRON(0) COMPLEXES

Abstract

Keywords

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