ADDITION OF ALKENES TO TRICARBONYL(VINYLKETENE)IRON(O) COMPLEXES AND THE SYNTHESIS OF CYCLOPROPANES

S P  SABERI; A M Z  SLAWIN; S E  THOMAS; D J  WILLIAMS; M F  WARD; P A  WORTHINGTON

ADDITION OF ALKENES TO TRICARBONYL(VINYLKETENE)IRON(O) COMPLEXES AND THE SYNTHESIS OF CYCLOPROPANES

S P SABERI, A M Z SLAWIN, S E THOMAS, D J WILLIAMS, M F WARD, P A WORTHINGTON

Research output: Contribution to journal › Article › peer-review

Abstract

The tricarbonyl(vinylketene)iron(o) complex 1 reacts with electron-poor alkenes to give decarbonylated adducts 3 and these are oxidised to tetrasubstituted cyclopropanes 4 using CAN; an X-ray crystal structure. analysis of the adduct formed from 1 and dimethyl fumarate define its relative stereochemistry.

Original language	English
Pages (from-to)	2169-2170
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	18
Publication status	Published - 21 Sept 1994

Keywords

CHROMIUM CARBENE COMPLEXES
ALKYNES
CONVERSION
PHENOLS

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@article{df99d4262d544f5c83fe278873b7a822,

title = "ADDITION OF ALKENES TO TRICARBONYL(VINYLKETENE)IRON(O) COMPLEXES AND THE SYNTHESIS OF CYCLOPROPANES",

abstract = "The tricarbonyl(vinylketene)iron(o) complex 1 reacts with electron-poor alkenes to give decarbonylated adducts 3 and these are oxidised to tetrasubstituted cyclopropanes 4 using CAN; an X-ray crystal structure. analysis of the adduct formed from 1 and dimethyl fumarate define its relative stereochemistry.",

keywords = "CHROMIUM CARBENE COMPLEXES, ALKYNES, CONVERSION, PHENOLS",

author = "SABERI, \{S P\} and SLAWIN, \{A M Z\} and THOMAS, \{S E\} and WILLIAMS, \{D J\} and WARD, \{M F\} and WORTHINGTON, \{P A\}",

year = "1994",

month = sep,

day = "21",

language = "English",

pages = "2169--2170",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "18",

}

TY - JOUR

T1 - ADDITION OF ALKENES TO TRICARBONYL(VINYLKETENE)IRON(O) COMPLEXES AND THE SYNTHESIS OF CYCLOPROPANES

AU - SABERI, S P

AU - SLAWIN, A M Z

AU - THOMAS, S E

AU - WILLIAMS, D J

AU - WARD, M F

AU - WORTHINGTON, P A

PY - 1994/9/21

Y1 - 1994/9/21

N2 - The tricarbonyl(vinylketene)iron(o) complex 1 reacts with electron-poor alkenes to give decarbonylated adducts 3 and these are oxidised to tetrasubstituted cyclopropanes 4 using CAN; an X-ray crystal structure. analysis of the adduct formed from 1 and dimethyl fumarate define its relative stereochemistry.

AB - The tricarbonyl(vinylketene)iron(o) complex 1 reacts with electron-poor alkenes to give decarbonylated adducts 3 and these are oxidised to tetrasubstituted cyclopropanes 4 using CAN; an X-ray crystal structure. analysis of the adduct formed from 1 and dimethyl fumarate define its relative stereochemistry.

KW - CHROMIUM CARBENE COMPLEXES

KW - ALKYNES

KW - CONVERSION

KW - PHENOLS

UR - https://www.scopus.com/pages/publications/37049088242

M3 - Article

SN - 0022-4936

SP - 2169

EP - 2170

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 18

ER -

ADDITION OF ALKENES TO TRICARBONYL(VINYLKETENE)IRON(O) COMPLEXES AND THE SYNTHESIS OF CYCLOPROPANES

Abstract

Keywords

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