Activation and reactivity of (NHC)Pd(allyl)Cl (NHC = N-heterocyclic carbene) complexes in cross-coupling reactions

M S  Viciu; R F  Germaneau; O  Navarro-Fernandez; E D  Stevens; Steven Patrick Nolan

doi:10.1021/om020804i

Activation and reactivity of (NHC)Pd(allyl)Cl (NHC = N-heterocyclic carbene) complexes in cross-coupling reactions

M S Viciu, R F Germaneau, O Navarro-Fernandez, E D Stevens, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

Mononuclear palladium-allyl complexes bearing one N-heterocyclic carbene (NHC) ligand have been synthesized. These complexes offer a straightforward entryway into a number of catalytic cycles by simple action of a base.

Original language	English
Pages (from-to)	5470-5472
Number of pages	3
Journal	Organometallics
Volume	21
Issue number	25
DOIs	https://doi.org/10.1021/om020804i
Publication status	Published - 9 Dec 2002

Keywords

PALLADIUM-CATALYZED AMINATION
ARYL HALIDES
ALPHA-ARYLATION
CHLORIDES
IODIDES
SYSTEM
CHEMISTRY
BROMIDES
KETONES
LIGANDS

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10.1021/om020804i

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title = "Activation and reactivity of (NHC)Pd(allyl)Cl (NHC = N-heterocyclic carbene) complexes in cross-coupling reactions",

abstract = "Mononuclear palladium-allyl complexes bearing one N-heterocyclic carbene (NHC) ligand have been synthesized. These complexes offer a straightforward entryway into a number of catalytic cycles by simple action of a base.",

keywords = "PALLADIUM-CATALYZED AMINATION, ARYL HALIDES, ALPHA-ARYLATION, CHLORIDES, IODIDES, SYSTEM, CHEMISTRY, BROMIDES, KETONES, LIGANDS",

author = "Viciu, {M S} and Germaneau, {R F} and O Navarro-Fernandez and Stevens, {E D} and Nolan, {Steven Patrick}",

year = "2002",

month = dec,

day = "9",

doi = "10.1021/om020804i",

language = "English",

volume = "21",

pages = "5470--5472",

journal = "Organometallics",

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publisher = "American Chemical Society (ACS)",

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T1 - Activation and reactivity of (NHC)Pd(allyl)Cl (NHC = N-heterocyclic carbene) complexes in cross-coupling reactions

AU - Viciu, M S

AU - Germaneau, R F

AU - Navarro-Fernandez, O

AU - Stevens, E D

AU - Nolan, Steven Patrick

PY - 2002/12/9

Y1 - 2002/12/9

N2 - Mononuclear palladium-allyl complexes bearing one N-heterocyclic carbene (NHC) ligand have been synthesized. These complexes offer a straightforward entryway into a number of catalytic cycles by simple action of a base.

AB - Mononuclear palladium-allyl complexes bearing one N-heterocyclic carbene (NHC) ligand have been synthesized. These complexes offer a straightforward entryway into a number of catalytic cycles by simple action of a base.

KW - PALLADIUM-CATALYZED AMINATION

KW - ARYL HALIDES

KW - ALPHA-ARYLATION

KW - CHLORIDES

KW - IODIDES

KW - SYSTEM

KW - CHEMISTRY

KW - BROMIDES

KW - KETONES

KW - LIGANDS

U2 - 10.1021/om020804i

DO - 10.1021/om020804i

M3 - Article

SN - 0276-7333

VL - 21

SP - 5470

EP - 5472

JO - Organometallics

JF - Organometallics

IS - 25

ER -

Activation and reactivity of (NHC)Pd(allyl)Cl (NHC = N-heterocyclic carbene) complexes in cross-coupling reactions

Abstract

Keywords

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