Activation and reactivity of (NHC)Pd(allyl)Cl (NHC = N-heterocyclic carbene) complexes in cross-coupling reactions

M S Viciu, R F Germaneau, O Navarro-Fernandez, E D Stevens, Steven Patrick Nolan

Research output: Contribution to journalArticlepeer-review

314 Citations (Scopus)

Abstract

Mononuclear palladium-allyl complexes bearing one N-heterocyclic carbene (NHC) ligand have been synthesized. These complexes offer a straightforward entryway into a number of catalytic cycles by simple action of a base.

Original languageEnglish
Pages (from-to)5470-5472
Number of pages3
JournalOrganometallics
Volume21
Issue number25
DOIs
Publication statusPublished - 9 Dec 2002

Keywords

  • PALLADIUM-CATALYZED AMINATION
  • ARYL HALIDES
  • ALPHA-ARYLATION
  • CHLORIDES
  • IODIDES
  • SYSTEM
  • CHEMISTRY
  • BROMIDES
  • KETONES
  • LIGANDS

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