Acetylacetonatodifluorooxometalates of vanadium and molybdenum: Syntheses and crystal structures

A. Stasch; M. Schormann; J. Prust; H. W. Roesky; H. G. Schmidt; M. Noltemeyer

doi:10.1039/b100740h

Acetylacetonatodifluorooxometalates of vanadium and molybdenum: Syntheses and crystal structures

A. Stasch, M. Schormann, J. Prust, H. W. Roesky^*, H. G. Schmidt, M. Noltemeyer

^*Corresponding author for this work

School of Chemistry

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Abstract

[Et₄N][HF₂] reacted with VO(acac)₂ and MoO₂(acac)₂ in acetonitrile at room temperature with elimination of Hacac to produce the metalates [Et₄N][(acac)VOF₂] 1 and [Et₄N][(acac)MoO₂F₂] 2, respectively. These compounds are the first examples of fluorometalates of vanadium and molybdenum bearing the acetylacetonato group. The crystal structures have been determined.

Original language	English
Pages (from-to)	1945-1947
Number of pages	3
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	13
DOIs	https://doi.org/10.1039/b100740h
Publication status	Published - 2001

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title = "Acetylacetonatodifluorooxometalates of vanadium and molybdenum: Syntheses and crystal structures",

abstract = "[Et4N][HF2] reacted with VO(acac)2 and MoO2(acac)2 in acetonitrile at room temperature with elimination of Hacac to produce the metalates [Et4N][(acac)VOF2] 1 and [Et4N][(acac)MoO2F2] 2, respectively. These compounds are the first examples of fluorometalates of vanadium and molybdenum bearing the acetylacetonato group. The crystal structures have been determined.",

author = "A. Stasch and M. Schormann and J. Prust and Roesky, \{H. W.\} and Schmidt, \{H. G.\} and M. Noltemeyer",

year = "2001",

doi = "10.1039/b100740h",

language = "English",

pages = "1945--1947",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1470-479X",

publisher = "Royal Society of Chemistry",

number = "13",

}

TY - JOUR

T1 - Acetylacetonatodifluorooxometalates of vanadium and molybdenum

T2 - Syntheses and crystal structures

AU - Stasch, A.

AU - Schormann, M.

AU - Prust, J.

AU - Roesky, H. W.

AU - Schmidt, H. G.

AU - Noltemeyer, M.

PY - 2001

Y1 - 2001

N2 - [Et4N][HF2] reacted with VO(acac)2 and MoO2(acac)2 in acetonitrile at room temperature with elimination of Hacac to produce the metalates [Et4N][(acac)VOF2] 1 and [Et4N][(acac)MoO2F2] 2, respectively. These compounds are the first examples of fluorometalates of vanadium and molybdenum bearing the acetylacetonato group. The crystal structures have been determined.

AB - [Et4N][HF2] reacted with VO(acac)2 and MoO2(acac)2 in acetonitrile at room temperature with elimination of Hacac to produce the metalates [Et4N][(acac)VOF2] 1 and [Et4N][(acac)MoO2F2] 2, respectively. These compounds are the first examples of fluorometalates of vanadium and molybdenum bearing the acetylacetonato group. The crystal structures have been determined.

UR - https://www.scopus.com/pages/publications/0034742956

U2 - 10.1039/b100740h

DO - 10.1039/b100740h

M3 - Article

AN - SCOPUS:0034742956

SN - 1470-479X

SP - 1945

EP - 1947

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 13

ER -

Acetylacetonatodifluorooxometalates of vanadium and molybdenum: Syntheses and crystal structures

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