Projects per year
Abstract
The gem-difluoromethylene (CF2) group significantly accelerates
ring-closing metathesis of 1,8-nonadienes relative to the methylene
(CH2) group demonstrating similar rate accelerations to that observed
for the classic Thorpe–Ingold substituents, diester malonates and ketals.
ring-closing metathesis of 1,8-nonadienes relative to the methylene
(CH2) group demonstrating similar rate accelerations to that observed
for the classic Thorpe–Ingold substituents, diester malonates and ketals.
| Original language | English |
|---|---|
| Pages (from-to) | 7201-7203 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 49 |
| Issue number | 65 |
| Early online date | 4 Jul 2013 |
| DOIs | |
| Publication status | Published - 21 Aug 2013 |
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Dive into the research topics of 'Accelerating influence of the gem-difluoromethylene group in a ring-closing olefin metathesis reaction. A Thorpe–Ingold effect?'. Together they form a unique fingerprint.Projects
- 2 Finished
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FUNCAT: EU FP7 ERC Advanced Grant - FUNCAT - Fundamental Studies in Organometallic Chemistry and Homogeneous Catalysis
Nolan, S. P. (PI)
1/01/09 → 31/12/14
Project: Standard
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EUMET: EU FP7 'EUMET' Olefin Metathesis as a Practical Synthetic Tool
Nolan, S. P. (PI)
1/11/08 → 31/10/12
Project: Standard