A three-dimensional hydrogen-bonded framework in 4,4 '-trimethylenedipiperidinium-2,5-dicarboxybenzene-1,4-dicarboxylate-water (1/1/1)

C J  Burchell; G  Ferguson; A J  Lough; C  Glidewell

A three-dimensional hydrogen-bonded framework in 4,4 '-trimethylenedipiperidinium-2,5-dicarboxybenzene-1,4-dicarboxylate-water (1/1/1)

C J Burchell, G Ferguson, A J Lough, C Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound is a salt, C13H28N22+.C10H4O82-.H2O. In the anion, there are two short intramolecular hydrogen bonds [O . . .O 2.395 (2) and 2.383 (2) Angstrom; O . . .H . . .O 175 and 172 degrees]. Pairs of anions and pairs of water molecules are linked by further O-H . . .O hydrogen bonds [O . . .O 2.756 (2) and 2.980 (2) Angstrom; O-H . . .O 171 and 175 degrees] into cyclic centrosymmetric R-6(6)(16) aggregates; these aggregates are linked via the cations into a three-dimensional framework by means of four distinct N-H . . .O hydrogen bonds [N . . .O 2.787 (2)- 3.204 (2) Angstrom; N-H . . .O 148-173 degrees].

Original language	English
Pages (from-to)	92-94
Number of pages	3
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	57
Publication status	Published - Jan 2001

Keywords

ACID PYROMELLITIC ACID

Cite this

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title = "A three-dimensional hydrogen-bonded framework in 4,4 '-trimethylenedipiperidinium-2,5-dicarboxybenzene-1,4-dicarboxylate-water (1/1/1)",

abstract = "The title compound is a salt, C13H28N22+.C10H4O82-.H2O. In the anion, there are two short intramolecular hydrogen bonds [O . . .O 2.395 (2) and 2.383 (2) Angstrom; O . . .H . . .O 175 and 172 degrees]. Pairs of anions and pairs of water molecules are linked by further O-H . . .O hydrogen bonds [O . . .O 2.756 (2) and 2.980 (2) Angstrom; O-H . . .O 171 and 175 degrees] into cyclic centrosymmetric R-6(6)(16) aggregates; these aggregates are linked via the cations into a three-dimensional framework by means of four distinct N-H . . .O hydrogen bonds [N . . .O 2.787 (2)- 3.204 (2) Angstrom; N-H . . .O 148-173 degrees].",

keywords = "ACID PYROMELLITIC ACID",

author = "Burchell, {C J} and G Ferguson and Lough, {A J} and C Glidewell",

year = "2001",

month = jan,

language = "English",

volume = "57",

pages = "92--94",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - A three-dimensional hydrogen-bonded framework in 4,4 '-trimethylenedipiperidinium-2,5-dicarboxybenzene-1,4-dicarboxylate-water (1/1/1)

AU - Burchell, C J

AU - Ferguson, G

AU - Lough, A J

AU - Glidewell, C

PY - 2001/1

Y1 - 2001/1

N2 - The title compound is a salt, C13H28N22+.C10H4O82-.H2O. In the anion, there are two short intramolecular hydrogen bonds [O . . .O 2.395 (2) and 2.383 (2) Angstrom; O . . .H . . .O 175 and 172 degrees]. Pairs of anions and pairs of water molecules are linked by further O-H . . .O hydrogen bonds [O . . .O 2.756 (2) and 2.980 (2) Angstrom; O-H . . .O 171 and 175 degrees] into cyclic centrosymmetric R-6(6)(16) aggregates; these aggregates are linked via the cations into a three-dimensional framework by means of four distinct N-H . . .O hydrogen bonds [N . . .O 2.787 (2)- 3.204 (2) Angstrom; N-H . . .O 148-173 degrees].

AB - The title compound is a salt, C13H28N22+.C10H4O82-.H2O. In the anion, there are two short intramolecular hydrogen bonds [O . . .O 2.395 (2) and 2.383 (2) Angstrom; O . . .H . . .O 175 and 172 degrees]. Pairs of anions and pairs of water molecules are linked by further O-H . . .O hydrogen bonds [O . . .O 2.756 (2) and 2.980 (2) Angstrom; O-H . . .O 171 and 175 degrees] into cyclic centrosymmetric R-6(6)(16) aggregates; these aggregates are linked via the cations into a three-dimensional framework by means of four distinct N-H . . .O hydrogen bonds [N . . .O 2.787 (2)- 3.204 (2) Angstrom; N-H . . .O 148-173 degrees].

KW - ACID PYROMELLITIC ACID

M3 - Article

SN - 1600-5759

VL - 57

SP - 92

EP - 94

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

A three-dimensional hydrogen-bonded framework in 4,4 '-trimethylenedipiperidinium-2,5-dicarboxybenzene-1,4-dicarboxylate-water (1/1/1)

Abstract

Keywords

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