A three-dimensional hydrogen-bonded framework in 2-amino-4,6-bis[N-methyl-N-(4-methylphenyl) amino]-pyrimidine-5-carbaldehyde and hydrogen-bonded sheets in 2-amino-4-(indolin-1-yl)-6-methoxypyrimidine-5-carbaldehyde

John N. Low; Jorge Trilleras; Justo Cobo; Antonio Marchal; Christopher Glidewell

doi:10.1107/S0108270107048809

A three-dimensional hydrogen-bonded framework in 2-amino-4,6-bis[N-methyl-N-(4-methylphenyl) amino]-pyrimidine-5-carbaldehyde and hydrogen-bonded sheets in 2-amino-4-(indolin-1-yl)-6-methoxypyrimidine-5-carbaldehyde

John N. Low, Jorge Trilleras, Justo Cobo, Antonio Marchal, Christopher Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The molecules of 2-amino-4,6-bis[N-methyl-N-(4- methylphenyl) amino]pyrimidine-5-carbaldehyde, C21H23N5O, (I), and 2-amino-4-(indolin-1-yl)-6-methoxypyrimidine-5-carbaldehyde, C14H14N4O2, (II), which crystallizes with Z' = 2 in the space group P (1) over bar, exhibit polarized electronic structures. Molecules of (I) are linked by a combination of N - H center dot center dot center dot O, C - H center dot center dot center dot O and C - H center dot center dot center dot pi(arene) hydrogen bonds into a three-dimensional framework structure, while those of (II) are linked into sheets by a combination of two N - H center dot center dot center dot O hydrogen bonds and one N - H center dot center dot center dot pi(arene) hydrogen bond.

Original language	English
Number of pages	4
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	63
DOIs	https://doi.org/10.1107/S0108270107048809
Publication status	Published - Nov 2007

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Low, J. N., Trilleras, J., Cobo, J., Marchal, A., & Glidewell, C. (2007). A three-dimensional hydrogen-bonded framework in 2-amino-4,6-bis[N-methyl-N-(4-methylphenyl) amino]-pyrimidine-5-carbaldehyde and hydrogen-bonded sheets in 2-amino-4-(indolin-1-yl)-6-methoxypyrimidine-5-carbaldehyde. Acta Crystallographica Section C-Crystal Structure Communications, 63. https://doi.org/10.1107/S0108270107048809

@article{abce253ef6f14975bcbd2488671b4083,

title = "A three-dimensional hydrogen-bonded framework in 2-amino-4,6-bis[N-methyl-N-(4-methylphenyl) amino]-pyrimidine-5-carbaldehyde and hydrogen-bonded sheets in 2-amino-4-(indolin-1-yl)-6-methoxypyrimidine-5-carbaldehyde",

abstract = "The molecules of 2-amino-4,6-bis[N-methyl-N-(4- methylphenyl) amino]pyrimidine-5-carbaldehyde, C21H23N5O, (I), and 2-amino-4-(indolin-1-yl)-6-methoxypyrimidine-5-carbaldehyde, C14H14N4O2, (II), which crystallizes with Z' = 2 in the space group P (1) over bar, exhibit polarized electronic structures. Molecules of (I) are linked by a combination of N - H center dot center dot center dot O, C - H center dot center dot center dot O and C - H center dot center dot center dot pi(arene) hydrogen bonds into a three-dimensional framework structure, while those of (II) are linked into sheets by a combination of two N - H center dot center dot center dot O hydrogen bonds and one N - H center dot center dot center dot pi(arene) hydrogen bond.",

author = "Low, {John N.} and Jorge Trilleras and Justo Cobo and Antonio Marchal and Christopher Glidewell",

year = "2007",

month = nov,

doi = "10.1107/S0108270107048809",

language = "English",

volume = "63",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

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Low, JN, Trilleras, J, Cobo, J, Marchal, A & Glidewell, C 2007, 'A three-dimensional hydrogen-bonded framework in 2-amino-4,6-bis[N-methyl-N-(4-methylphenyl) amino]-pyrimidine-5-carbaldehyde and hydrogen-bonded sheets in 2-amino-4-(indolin-1-yl)-6-methoxypyrimidine-5-carbaldehyde', Acta Crystallographica Section C-Crystal Structure Communications, vol. 63. https://doi.org/10.1107/S0108270107048809

A three-dimensional hydrogen-bonded framework in 2-amino-4,6-bis[N-methyl-N-(4-methylphenyl) amino]-pyrimidine-5-carbaldehyde and hydrogen-bonded sheets in 2-amino-4-(indolin-1-yl)-6-methoxypyrimidine-5-carbaldehyde. / Low, John N.; Trilleras, Jorge; Cobo, Justo et al.
In: Acta Crystallographica Section C-Crystal Structure Communications, Vol. 63, 11.2007.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A three-dimensional hydrogen-bonded framework in 2-amino-4,6-bis[N-methyl-N-(4-methylphenyl) amino]-pyrimidine-5-carbaldehyde and hydrogen-bonded sheets in 2-amino-4-(indolin-1-yl)-6-methoxypyrimidine-5-carbaldehyde

AU - Low, John N.

AU - Trilleras, Jorge

AU - Cobo, Justo

AU - Marchal, Antonio

AU - Glidewell, Christopher

PY - 2007/11

Y1 - 2007/11

N2 - The molecules of 2-amino-4,6-bis[N-methyl-N-(4- methylphenyl) amino]pyrimidine-5-carbaldehyde, C21H23N5O, (I), and 2-amino-4-(indolin-1-yl)-6-methoxypyrimidine-5-carbaldehyde, C14H14N4O2, (II), which crystallizes with Z' = 2 in the space group P (1) over bar, exhibit polarized electronic structures. Molecules of (I) are linked by a combination of N - H center dot center dot center dot O, C - H center dot center dot center dot O and C - H center dot center dot center dot pi(arene) hydrogen bonds into a three-dimensional framework structure, while those of (II) are linked into sheets by a combination of two N - H center dot center dot center dot O hydrogen bonds and one N - H center dot center dot center dot pi(arene) hydrogen bond.

AB - The molecules of 2-amino-4,6-bis[N-methyl-N-(4- methylphenyl) amino]pyrimidine-5-carbaldehyde, C21H23N5O, (I), and 2-amino-4-(indolin-1-yl)-6-methoxypyrimidine-5-carbaldehyde, C14H14N4O2, (II), which crystallizes with Z' = 2 in the space group P (1) over bar, exhibit polarized electronic structures. Molecules of (I) are linked by a combination of N - H center dot center dot center dot O, C - H center dot center dot center dot O and C - H center dot center dot center dot pi(arene) hydrogen bonds into a three-dimensional framework structure, while those of (II) are linked into sheets by a combination of two N - H center dot center dot center dot O hydrogen bonds and one N - H center dot center dot center dot pi(arene) hydrogen bond.

U2 - 10.1107/S0108270107048809

DO - 10.1107/S0108270107048809

M3 - Article

SN - 1600-5759

VL - 63

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

Low JN, Trilleras J, Cobo J, Marchal A, Glidewell C. A three-dimensional hydrogen-bonded framework in 2-amino-4,6-bis[N-methyl-N-(4-methylphenyl) amino]-pyrimidine-5-carbaldehyde and hydrogen-bonded sheets in 2-amino-4-(indolin-1-yl)-6-methoxypyrimidine-5-carbaldehyde. Acta Crystallographica Section C-Crystal Structure Communications. 2007 Nov;63. doi: 10.1107/S0108270107048809