TY - JOUR
T1 - A structural hierarchy in the hydrogen-bonded adduct N,N'-dimethylpiperazine-tartaric acid-water (1/2/2): an N-component, N-dimensional structure (N = 3) with substructures having N = 1 and 2
AU - Farrell, MM
AU - Ferguson, G
AU - Lough, AJ
AU - Glidewell, Christopher
PY - 2002/1
Y1 - 2002/1
N2 - In the hydrated adduct N,N'-dimethylpiperazine-1,4-diium bis(3-carboxy-2,3-dihydroxypropanoate) dihydrate, [MeNH(CH2CH2)(2)NHMe](2+).2(C4H5O6)(-).2H(2)O or C6H16N22+. 2C(4)H(5)O(6)(-).2H(2)O, formed between racemic tartaric acid and N,N'-dimethylpiperazine (triclinic P (1) over bar, Z' = 0.5), the cations lie across centres of inversion. The anions alone form chains, and anions and water molecules together form sheets; the sheets are linked by the cations to form a pillared-layer framework. The supramolecular architecture thus takes the form of a family of N-dimensional N-component structures having N = 1, 2 or 3.
AB - In the hydrated adduct N,N'-dimethylpiperazine-1,4-diium bis(3-carboxy-2,3-dihydroxypropanoate) dihydrate, [MeNH(CH2CH2)(2)NHMe](2+).2(C4H5O6)(-).2H(2)O or C6H16N22+. 2C(4)H(5)O(6)(-).2H(2)O, formed between racemic tartaric acid and N,N'-dimethylpiperazine (triclinic P (1) over bar, Z' = 0.5), the cations lie across centres of inversion. The anions alone form chains, and anions and water molecules together form sheets; the sheets are linked by the cations to form a pillared-layer framework. The supramolecular architecture thus takes the form of a family of N-dimensional N-component structures having N = 1, 2 or 3.
U2 - 10.1107/S0108270101017449
DO - 10.1107/S0108270101017449
M3 - Article
SN - 0108-2701
VL - C58
SP - o6-o8
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
ER -