A simple synthetic entryway into palladium cross-coupling catalysis

Caroline M. Zinser; Fady Nahra; Marcel Brill; Rebecca E. Meadows; David B. Cordes; Alexandra M. Z. Slawin; Steven P. Nolan; Catherine S. J. Cazin

doi:10.1039/c7cc02487h

A simple synthetic entryway into palladium cross-coupling catalysis

Caroline M. Zinser, Fady Nahra, Marcel Brill, Rebecca E. Meadows, David B. Cordes, Alexandra M. Z. Slawin, Steven P. Nolan, Catherine S. J. Cazin

Research output: Contribution to journal › Article › peer-review

57 Citations (Scopus)

Abstract

The simple synthesis of a family of palladates containing an imidazolium counterion is presented. These ''ate'' complexes can be easily converted into well-defined palladium-N-heterocyclic carbene (NHC) complexes. The synthetic protocols leading to the ''ate'' and to the Pd-NHC neutral complexes have been exemplified with various NHC ligands. The palladates prove efficient pre-catalysts enabling Suzuki-Miyaura and Mizoroki-Heck reactions.

Original language	English
Pages (from-to)	7990-7993
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	57
Early online date	11 May 2017
DOIs	https://doi.org/10.1039/c7cc02487h
Publication status	Published - 21 Jul 2017

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10.1039/c7cc02487h

Alexandra Martha Zoya Slawin
- amzsst-andrews.acuk
- School of Chemistry - Emeritus Professor
- EaSTCHEM
Person: Emeritus Professor

A simple synthetic entryway into palladium cross-coupling catalysis (dataset)
Zinser, C. M. (Creator), Nahra, F. (Creator), Brill, M. (Creator), Meadows, R. E. (Creator), Cordes, D. B. (Creator), Slawin, A. M. Z. (Creator), Nolan, S. P. (Creator) & Cazin, C. S. J. (Creator), Cambridge Crystallographic Data Centre, 28 Nov 2015
https://dx.doi.org/10.1039/C7CC02487H
Dataset

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title = "A simple synthetic entryway into palladium cross-coupling catalysis",

abstract = "The simple synthesis of a family of palladates containing an imidazolium counterion is presented. These ''ate'' complexes can be easily converted into well-defined palladium-N-heterocyclic carbene (NHC) complexes. The synthetic protocols leading to the ''ate'' and to the Pd-NHC neutral complexes have been exemplified with various NHC ligands. The palladates prove efficient pre-catalysts enabling Suzuki-Miyaura and Mizoroki-Heck reactions.",

author = "Zinser, {Caroline M.} and Fady Nahra and Marcel Brill and Meadows, {Rebecca E.} and Cordes, {David B.} and Slawin, {Alexandra M. Z.} and Nolan, {Steven P.} and Cazin, {Catherine S. J.}",

note = "The Royal Society (University Research Fellowship to C. S. J. C.), AstraZeneca (Studentship to C. M. Z.) and the ERC (Advanced grant to S. P. N.) are acknowledged for their support of this work.",

year = "2017",

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doi = "10.1039/c7cc02487h",

language = "English",

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T1 - A simple synthetic entryway into palladium cross-coupling catalysis

AU - Zinser, Caroline M.

AU - Nahra, Fady

AU - Brill, Marcel

AU - Meadows, Rebecca E.

AU - Cordes, David B.

AU - Slawin, Alexandra M. Z.

AU - Nolan, Steven P.

AU - Cazin, Catherine S. J.

N1 - The Royal Society (University Research Fellowship to C. S. J. C.), AstraZeneca (Studentship to C. M. Z.) and the ERC (Advanced grant to S. P. N.) are acknowledged for their support of this work.

PY - 2017/7/21

Y1 - 2017/7/21

N2 - The simple synthesis of a family of palladates containing an imidazolium counterion is presented. These ''ate'' complexes can be easily converted into well-defined palladium-N-heterocyclic carbene (NHC) complexes. The synthetic protocols leading to the ''ate'' and to the Pd-NHC neutral complexes have been exemplified with various NHC ligands. The palladates prove efficient pre-catalysts enabling Suzuki-Miyaura and Mizoroki-Heck reactions.

AB - The simple synthesis of a family of palladates containing an imidazolium counterion is presented. These ''ate'' complexes can be easily converted into well-defined palladium-N-heterocyclic carbene (NHC) complexes. The synthetic protocols leading to the ''ate'' and to the Pd-NHC neutral complexes have been exemplified with various NHC ligands. The palladates prove efficient pre-catalysts enabling Suzuki-Miyaura and Mizoroki-Heck reactions.

U2 - 10.1039/c7cc02487h

DO - 10.1039/c7cc02487h

M3 - Article

SN - 1359-7345

VL - 53

SP - 7990

EP - 7993

JO - Chemical Communications

JF - Chemical Communications

IS - 57

ER -

A simple synthetic entryway into palladium cross-coupling catalysis

Abstract

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Alexandra Martha Zoya Slawin

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A simple synthetic entryway into palladium cross-coupling catalysis (dataset)

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