A simple access to transition metal cyclopropenylidene complexes

Yannick Daniel Bidal; Mathieu Lesieur; Mohand  Melaimi; David Bradford Cordes; Alexandra Martha Zoya Slawin; Guy  Bertrand; Catherine S.J. Cazin

doi:10.1039/C4CC10375K

A simple access to transition metal cyclopropenylidene complexes

Yannick Daniel Bidal, Mathieu Lesieur, Mohand Melaimi, David Bradford Cordes, Alexandra Martha Zoya Slawin, Guy Bertrand , Catherine S.J. Cazin

Research output: Contribution to journal › Article › peer-review

Abstract

We report the first example of BAC–Cu complex (BAC = bis(diisopropylamino)cyclopropenylidene) and its use as a carbene-transfer reagent, allowing access to Au–, Pd–, Ir– and Rh–BAC compounds. Catalytic experiments show the high activity of the [CuCl(BAC)] complex in Click chemistry.

Original language	English
Pages (from-to)	4778-4781
Journal	Chemical Communications
Volume	51
Issue number	23
Early online date	16 Feb 2015
DOIs	https://doi.org/10.1039/C4CC10375K
Publication status	Published - 21 Mar 2015

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Cazin_2015_ChemComm_Simple_AM
Copyright the Authors 2015. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at http://doi.org/10.1039/C4CC10375K
Accepted author manuscript, 873 KB

Structuring the Future: Structuring the Future - Underpinning world-leading science in EaStCHEM through cutting edge characterisation
Woollins, J. D. (PI), Ashbrook, S. E. (CoI), Morris, R. (CoI) & Slawin, A. (CoI)
EPSRC
1/01/13 → 31/03/13
Project: Standard
Upgrade Small Equipment Base: Small items of research equipment at the University of St Andrews. Supporting a new generation of physical sciences research
Woollins, J. D. (PI)
EPSRC
1/11/12 → 31/03/13
Project: Standard
Catalytic C-H bond functionalisation: Catalytic C-H bond functionalisation
Cazin, C. S. J. (PI)
The Royal Society
1/10/11 → 6/05/17
Project: Fellowship

Alexandra Slawin
- amzsst-andrews.acuk
- School of Chemistry - Emeritus Professor
- EaSTCHEM
Person: Emeritus Professor

A simple access to transition metal cyclopropenylidene complexes
Bidal, Y. D. (Creator), Lesieur, M. (Creator), Melaimi, M. (Creator), Cordes, D. B. (Creator), Slawin, A. M. Z. (Creator) & Cazin, C. S. J. (Creator), Cambridge Crystallographic Data Centre, 2015
https://dx.doi.org/10.5517/cc138bh6 and 4 more links, https://dx.doi.org/10.5517/cc12zzst, https://dx.doi.org/10.5517/cc12zztv, https://dx.doi.org/10.5517/cc12zzvw, https://dx.doi.org/10.5517/cc12zzwx (show fewer)
Dataset

Cite this

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title = "A simple access to transition metal cyclopropenylidene complexes",

abstract = "We report the first example of BAC–Cu complex (BAC = bis(diisopropylamino)cyclopropenylidene) and its use as a carbene-transfer reagent, allowing access to Au–, Pd–, Ir– and Rh–BAC compounds. Catalytic experiments show the high activity of the [CuCl(BAC)] complex in Click chemistry.",

author = "Bidal, {Yannick Daniel} and Mathieu Lesieur and Mohand Melaimi and Cordes, {David Bradford} and Slawin, {Alexandra Martha Zoya} and Guy Bertrand and Cazin, {Catherine S.J.}",

note = "The authors gratefully acknowledge the Royal Society (University Research Fellowship to CSJC) and the DOE (DE-FG02-13ER16370) for financial support.",

year = "2015",

month = mar,

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doi = "10.1039/C4CC10375K",

language = "English",

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T1 - A simple access to transition metal cyclopropenylidene complexes

AU - Bidal, Yannick Daniel

AU - Lesieur, Mathieu

AU - Melaimi, Mohand

AU - Cordes, David Bradford

AU - Slawin, Alexandra Martha Zoya

AU - Bertrand , Guy

AU - Cazin, Catherine S.J.

N1 - The authors gratefully acknowledge the Royal Society (University Research Fellowship to CSJC) and the DOE (DE-FG02-13ER16370) for financial support.

PY - 2015/3/21

Y1 - 2015/3/21

N2 - We report the first example of BAC–Cu complex (BAC = bis(diisopropylamino)cyclopropenylidene) and its use as a carbene-transfer reagent, allowing access to Au–, Pd–, Ir– and Rh–BAC compounds. Catalytic experiments show the high activity of the [CuCl(BAC)] complex in Click chemistry.

AB - We report the first example of BAC–Cu complex (BAC = bis(diisopropylamino)cyclopropenylidene) and its use as a carbene-transfer reagent, allowing access to Au–, Pd–, Ir– and Rh–BAC compounds. Catalytic experiments show the high activity of the [CuCl(BAC)] complex in Click chemistry.

U2 - 10.1039/C4CC10375K

DO - 10.1039/C4CC10375K

M3 - Article

C2 - 25621852

SN - 1359-7345

VL - 51

SP - 4778

EP - 4781

JO - Chemical Communications

JF - Chemical Communications

IS - 23

ER -

A simple access to transition metal cyclopropenylidene complexes

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Projects

Structuring the Future: Structuring the Future - Underpinning world-leading science in EaStCHEM through cutting edge characterisation

Upgrade Small Equipment Base: Small items of research equipment at the University of St Andrews. Supporting a new generation of physical sciences research

Catalytic C-H bond functionalisation: Catalytic C-H bond functionalisation

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Alexandra Slawin

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A simple access to transition metal cyclopropenylidene complexes

Cite this