A Silver(I) Iodide Complex of a Tellurophosphorane

Andreas Nordheider; Alexandra Martha Zoya Slawin; J Derek Woollins; Tristram  Chivers

doi:10.1002/zaac.201400452

A Silver(I) Iodide Complex of a Tellurophosphorane

Andreas Nordheider, Alexandra Martha Zoya Slawin, J Derek Woollins, Tristram Chivers

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

9 Downloads (Pure)

Abstract

The formation and structural characterization of the first coordination complex of the tellurophosphorane [tBu(H)NP(μ-NtBu)₂P(Te)N(H)tBu] are presented. The silver(I) iodide complex {(I)Ag[tBu(H)NP(μ-NtBu)₂P(Te)N(H)tBu]₃} (2) was isolated from the reaction of [Li(TMEDA)]₂[tBuN(Te)P(μ-NtBu)₂P(Te)NtBu)] (1) with AgI in toluene and characterized by X-ray analysis and multinuclear NMR spectroscopy. Complex 2 is comprised of three tellurophosphorane ligands coordinated to AgI in a distorted tetrahedral arrangement [102.90(3)–114.51(5)^o]. The P=Te bond lengths of 2.3883(13)–2.4043(17) Å in 2 are slightly elongated compared to those in the free ligand.

Original language	English
Pages (from-to)	405-407
Journal	Zeitschrift für Anorganische und Allgemeine Chemie
Volume	641
Issue number	2
Early online date	26 Nov 2014
DOIs	https://doi.org/10.1002/zaac.201400452
Publication status	Published - Feb 2015

Keywords

Phosphorus
Tellurium
Silver
Cyclodiphosphazane
Crystal structure

Access to Document

10.1002/zaac.201400452

Woollins_2015_ZAAC_Silver_AM
Copyright © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This is the accepted version of the following article: Nordheider, A., Slawin, A. M. Z., Woollins, J. D. and Chivers, T. (2015), A Silver(I) Iodide Complex of a Tellurophosphorane. Z. anorg. allg. Chem., 641: 405–407, which has been published in final form at http://dx.doi.org/10.1002/zaac.201400452
Accepted author manuscript, 466 KB

Impact Acceleration Account: Impact Acceleration Account
Woollins, J. D. (PI)
EPSRC
1/10/15 → 31/03/17
Project: Standard
Structuring the Future: Structuring the Future - Underpinning world-leading science in EaStCHEM through cutting edge characterisation
Woollins, J. D. (PI), Ashbrook, S. E. (CoI), Morris, R. E. (CoI) & Slawin, A. M. Z. (CoI)
EPSRC
1/01/13 → 31/03/13
Project: Standard
Upgrade Small Equipment Base: Small items of research equipment at the University of St Andrews. Supporting a new generation of physical sciences research
Woollins, J. D. (PI)
EPSRC
1/11/12 → 31/03/13
Project: Standard

A Silver(I) Iodide Complex of a Tellurophosphorane (dataset)
Nordheider, A. (Creator), Slawin, A. M. Z. (Creator) & Woollins, J. D. (Creator), Cambridge Crystallographic Data Centre, 2015
https://dx.doi.org/10.5517/cc13fyr7
Dataset

Cite this

@article{1372e832357d4879a77c3cc9f0528707,

title = "A Silver(I) Iodide Complex of a Tellurophosphorane",

abstract = "The formation and structural characterization of the first coordination complex of the tellurophosphorane [tBu(H)NP(μ-NtBu)2P(Te)N(H)tBu] are presented. The silver(I) iodide complex {(I)Ag[tBu(H)NP(μ-NtBu)2P(Te)N(H)tBu]3} (2) was isolated from the reaction of [Li(TMEDA)]2[tBuN(Te)P(μ-NtBu)2P(Te)NtBu)] (1) with AgI in toluene and characterized by X-ray analysis and multinuclear NMR spectroscopy. Complex 2 is comprised of three tellurophosphorane ligands coordinated to AgI in a distorted tetrahedral arrangement [102.90(3)–114.51(5)o]. The P=Te bond lengths of 2.3883(13)–2.4043(17) {\AA} in 2 are slightly elongated compared to those in the free ligand.",

keywords = "Phosphorus, Tellurium, Silver, Cyclodiphosphazane, Crystal structure",

author = "Andreas Nordheider and Slawin, {Alexandra Martha Zoya} and Woollins, {J Derek} and Tristram Chivers",

note = "The authors acknowledge the EPSRC and NSERC (Canada) for support. ",

year = "2015",

month = feb,

doi = "10.1002/zaac.201400452",

language = "English",

volume = "641",

pages = "405--407",

journal = "Zeitschrift f{\"u}r Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH, Weinheim",

number = "2",

}

TY - JOUR

T1 - A Silver(I) Iodide Complex of a Tellurophosphorane

AU - Nordheider, Andreas

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, J Derek

AU - Chivers, Tristram

N1 - The authors acknowledge the EPSRC and NSERC (Canada) for support.

PY - 2015/2

Y1 - 2015/2

N2 - The formation and structural characterization of the first coordination complex of the tellurophosphorane [tBu(H)NP(μ-NtBu)2P(Te)N(H)tBu] are presented. The silver(I) iodide complex {(I)Ag[tBu(H)NP(μ-NtBu)2P(Te)N(H)tBu]3} (2) was isolated from the reaction of [Li(TMEDA)]2[tBuN(Te)P(μ-NtBu)2P(Te)NtBu)] (1) with AgI in toluene and characterized by X-ray analysis and multinuclear NMR spectroscopy. Complex 2 is comprised of three tellurophosphorane ligands coordinated to AgI in a distorted tetrahedral arrangement [102.90(3)–114.51(5)o]. The P=Te bond lengths of 2.3883(13)–2.4043(17) Å in 2 are slightly elongated compared to those in the free ligand.

AB - The formation and structural characterization of the first coordination complex of the tellurophosphorane [tBu(H)NP(μ-NtBu)2P(Te)N(H)tBu] are presented. The silver(I) iodide complex {(I)Ag[tBu(H)NP(μ-NtBu)2P(Te)N(H)tBu]3} (2) was isolated from the reaction of [Li(TMEDA)]2[tBuN(Te)P(μ-NtBu)2P(Te)NtBu)] (1) with AgI in toluene and characterized by X-ray analysis and multinuclear NMR spectroscopy. Complex 2 is comprised of three tellurophosphorane ligands coordinated to AgI in a distorted tetrahedral arrangement [102.90(3)–114.51(5)o]. The P=Te bond lengths of 2.3883(13)–2.4043(17) Å in 2 are slightly elongated compared to those in the free ligand.

KW - Phosphorus

KW - Tellurium

KW - Silver

KW - Cyclodiphosphazane

KW - Crystal structure

U2 - 10.1002/zaac.201400452

DO - 10.1002/zaac.201400452

M3 - Article

SN - 0044-2313

VL - 641

SP - 405

EP - 407

JO - Zeitschrift für Anorganische und Allgemeine Chemie

JF - Zeitschrift für Anorganische und Allgemeine Chemie

IS - 2

ER -

A Silver(I) Iodide Complex of a Tellurophosphorane

Abstract

Keywords

Access to Document

Fingerprint

Projects

Impact Acceleration Account: Impact Acceleration Account

Structuring the Future: Structuring the Future - Underpinning world-leading science in EaStCHEM through cutting edge characterisation

Upgrade Small Equipment Base: Small items of research equipment at the University of St Andrews. Supporting a new generation of physical sciences research

Datasets

A Silver(I) Iodide Complex of a Tellurophosphorane (dataset)

Cite this