A reactive nitrone-based organogel that self-assembles from its constituents in chloroform

Josh Richards; Douglas Philp

doi:10.1039/C6CC01259K

A reactive nitrone-based organogel that self-assembles from its constituents in chloroform

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Abstract

The reversible reaction of an aldehyde with a hydroxylamine affords a nitrone which is capable of forming a stiff gel with chloroform at concentrations as low as 0.20 wt% (6 mM). The gelator forms dynamically from its constituents and the gel assembly can be degraded in a controlled manner through a recognition-mediated reaction that targets the nitrone component of the gel network.

Original language	English
Pages (from-to)	4995-4998
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	28
Early online date	25 Feb 2016
DOIs	https://doi.org/10.1039/C6CC01259K
Publication status	Published - 11 Apr 2016

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10.1039/C6CC01259K

CC-COM-02-2016-001259.R1
Copyright 2016 the Authors. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1039/C6CC01259K
Accepted author manuscript, 13.4 MB

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abstract = "The reversible reaction of an aldehyde with a hydroxylamine affords a nitrone which is capable of forming a stiff gel with chloroform at concentrations as low as 0.20 wt\% (6 mM). The gelator forms dynamically from its constituents and the gel assembly can be degraded in a controlled manner through a recognition-mediated reaction that targets the nitrone component of the gel network.",

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AB - The reversible reaction of an aldehyde with a hydroxylamine affords a nitrone which is capable of forming a stiff gel with chloroform at concentrations as low as 0.20 wt% (6 mM). The gelator forms dynamically from its constituents and the gel assembly can be degraded in a controlled manner through a recognition-mediated reaction that targets the nitrone component of the gel network.

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A reactive nitrone-based organogel that self-assembles from its constituents in chloroform

Abstract

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A reactive nitrone-based organogel that self-assembles from its constituents in chloroform

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