A pyridine-containing ruthenium-indenylidene complex: Synthesis and activity in ring-closing metathesis

Herve Clavier; Jeffrey L. Petersen; Steven Patrick Nolan

doi:10.1016/j.jorganchem.2006.08.007

A pyridine-containing ruthenium-indenylidene complex: Synthesis and activity in ring-closing metathesis

Herve Clavier, Jeffrey L. Petersen, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of Cl2Ru(PCy3)(2)(3-phenylindenylidene) with excess pyridine leads to the new pyridine-containing ruthenium-based complex: Cl2Ru(PCy3)(Py)(2)(3-phenylindenylidene) in good yield. This catalyst has been fully characterized and tested in ring-closing metathesis. its moderate activity has been examined by kinetic studies using several substrates and different reaction conditions. (c) 2006 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	5444-5447
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	691
Issue number	24-25
DOIs	https://doi.org/10.1016/j.jorganchem.2006.08.007
Publication status	Published - 1 Dec 2006

Keywords

ruthenium
metathesis
ring-closing metathesis
indenylidene
ALKYLIDENE COMPLEXES
CARBENE COMPLEXES
CROSS-METATHESIS
CATALYSTS
LIGANDS
MECHANISM
BEARING
NHC

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10.1016/j.jorganchem.2006.08.007

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title = "A pyridine-containing ruthenium-indenylidene complex: Synthesis and activity in ring-closing metathesis",

abstract = "The reaction of Cl2Ru(PCy3)(2)(3-phenylindenylidene) with excess pyridine leads to the new pyridine-containing ruthenium-based complex: Cl2Ru(PCy3)(Py)(2)(3-phenylindenylidene) in good yield. This catalyst has been fully characterized and tested in ring-closing metathesis. its moderate activity has been examined by kinetic studies using several substrates and different reaction conditions. (c) 2006 Elsevier B.V. All rights reserved.",

keywords = "ruthenium, metathesis, ring-closing metathesis, indenylidene, ALKYLIDENE COMPLEXES, CARBENE COMPLEXES, CROSS-METATHESIS, CATALYSTS, LIGANDS, MECHANISM, BEARING, NHC",

author = "Herve Clavier and Petersen, {Jeffrey L.} and Nolan, {Steven Patrick}",

year = "2006",

month = dec,

day = "1",

doi = "10.1016/j.jorganchem.2006.08.007",

language = "English",

volume = "691",

pages = "5444--5447",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "24-25",

}

TY - JOUR

T1 - A pyridine-containing ruthenium-indenylidene complex: Synthesis and activity in ring-closing metathesis

AU - Clavier, Herve

AU - Petersen, Jeffrey L.

AU - Nolan, Steven Patrick

PY - 2006/12/1

Y1 - 2006/12/1

N2 - The reaction of Cl2Ru(PCy3)(2)(3-phenylindenylidene) with excess pyridine leads to the new pyridine-containing ruthenium-based complex: Cl2Ru(PCy3)(Py)(2)(3-phenylindenylidene) in good yield. This catalyst has been fully characterized and tested in ring-closing metathesis. its moderate activity has been examined by kinetic studies using several substrates and different reaction conditions. (c) 2006 Elsevier B.V. All rights reserved.

AB - The reaction of Cl2Ru(PCy3)(2)(3-phenylindenylidene) with excess pyridine leads to the new pyridine-containing ruthenium-based complex: Cl2Ru(PCy3)(Py)(2)(3-phenylindenylidene) in good yield. This catalyst has been fully characterized and tested in ring-closing metathesis. its moderate activity has been examined by kinetic studies using several substrates and different reaction conditions. (c) 2006 Elsevier B.V. All rights reserved.

KW - ruthenium

KW - metathesis

KW - ring-closing metathesis

KW - indenylidene

KW - ALKYLIDENE COMPLEXES

KW - CARBENE COMPLEXES

KW - CROSS-METATHESIS

KW - CATALYSTS

KW - LIGANDS

KW - MECHANISM

KW - BEARING

KW - NHC

UR - http://www.scopus.com/inward/record.url?scp=33751249602&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2006.08.007

DO - 10.1016/j.jorganchem.2006.08.007

M3 - Article

SN - 0022-328X

VL - 691

SP - 5444

EP - 5447

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 24-25

ER -

A pyridine-containing ruthenium-indenylidene complex: Synthesis and activity in ring-closing metathesis

Abstract

Keywords

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