A pyrazolate-stabilized sodium hydride complex

Andreas Stasch

doi:10.1039/c5cc00996k

A pyrazolate-stabilized sodium hydride complex

Andreas Stasch

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of a sterically demanding sodium pyrazolate complex with n-butylsodium and diphenylsilane afforded the first well-defined molecular sodium hydride complex [(pz)₆Na₇H] 1 (pz = 3,5-di-tert-butylpyrazolate) that could be structurally characterised.

Original language	English
Pages (from-to)	5056 - 5058
Number of pages	3
Journal	Chemical Communications
Volume	51
Issue number	24
Early online date	12 Feb 2015
DOIs	https://doi.org/10.1039/c5cc00996k
Publication status	Published - 25 Mar 2015

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10.1039/c5cc00996k

A pyrazolate-stabilized sodium hydride complex (dataset)
Stasch, A. (Creator), Cambridge Crystallographic Data Centre, 2015
https://dx.doi.org/10.5517/cc140rtq and one more link, https://dx.doi.org/10.5517/cc140rvr (show fewer)
Dataset

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title = "A pyrazolate-stabilized sodium hydride complex",

abstract = "The reaction of a sterically demanding sodium pyrazolate complex with n-butylsodium and diphenylsilane afforded the first well-defined molecular sodium hydride complex [(pz)6Na7H] 1 (pz = 3,5-di-tert-butylpyrazolate) that could be structurally characterised.",

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AB - The reaction of a sterically demanding sodium pyrazolate complex with n-butylsodium and diphenylsilane afforded the first well-defined molecular sodium hydride complex [(pz)6Na7H] 1 (pz = 3,5-di-tert-butylpyrazolate) that could be structurally characterised.

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DO - 10.1039/c5cc00996k

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SP - 5056

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JO - Chemical Communications

JF - Chemical Communications

IS - 24

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A pyrazolate-stabilized sodium hydride complex

Abstract

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Datasets

A pyrazolate-stabilized sodium hydride complex (dataset)

Cite this