A planar dianionic ditelluride and a cyclic tritelluride supported by P2N2 rings

Andreas Nordheider; Tristram Chivers; Ramalingam Thirumoorthi; Kasun S. Athukorala Arachchige; Alexandra M. Z. Slawin; J. Derek Woollins; Ignacio Vargas-Baca

doi:10.1039/c2dt32716c

A planar dianionic ditelluride and a cyclic tritelluride supported by P2N2 rings

Andreas Nordheider, Tristram Chivers^*, Ramalingam Thirumoorthi, Kasun S. Athukorala Arachchige, Alexandra M. Z. Slawin, J. Derek Woollins, Ignacio Vargas-Baca

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Oxidation of alkali metal derivatives of [Te((BuN)-Bu-t) P(mu-(NBu)-Bu-t)(2)P((NBu)-Bu-t)Te](2-)with I-2 produces the intermediate ditelluride dianion [Te((BuN)-Bu-t)P(mu-(NBu)-Bu-t)(2)P((NBu)-Bu-t)Te](2)(2-) with a planar PTeTeP conformation and, subsequently, the cyclic tritelluride [((BuN)-Bu-t)P(mu-(NBu)-Bu-t)(2)P((NBu)-Bu-t)(mu-TeTeTe)].

Original language	English
Pages (from-to)	3291-3294
Number of pages	4
Journal	Dalton Transactions
Volume	42
Issue number	10
Early online date	13 Dec 2012
DOIs	https://doi.org/10.1039/c2dt32716c
Publication status	Published - 2013

Keywords

X-ray structure
Crystal structure
Macrocycles
Anion

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title = "A planar dianionic ditelluride and a cyclic tritelluride supported by P2N2 rings",

abstract = "Oxidation of alkali metal derivatives of [Te((BuN)-Bu-t) P(mu-(NBu)-Bu-t)(2)P((NBu)-Bu-t)Te](2-)with I-2 produces the intermediate ditelluride dianion [Te((BuN)-Bu-t)P(mu-(NBu)-Bu-t)(2)P((NBu)-Bu-t)Te](2)(2-) with a planar PTeTeP conformation and, subsequently, the cyclic tritelluride [((BuN)-Bu-t)P(mu-(NBu)-Bu-t)(2)P((NBu)-Bu-t)(mu-TeTeTe)].",

keywords = "X-ray structure , Crystal structure, Macrocycles, Anion",

author = "Andreas Nordheider and Tristram Chivers and Ramalingam Thirumoorthi and Arachchige, {Kasun S. Athukorala} and Slawin, {Alexandra M. Z.} and Woollins, {J. Derek} and Ignacio Vargas-Baca",

year = "2013",

doi = "10.1039/c2dt32716c",

language = "English",

volume = "42",

pages = "3291--3294",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "10",

}

TY - JOUR

T1 - A planar dianionic ditelluride and a cyclic tritelluride supported by P2N2 rings

AU - Nordheider, Andreas

AU - Chivers, Tristram

AU - Thirumoorthi, Ramalingam

AU - Arachchige, Kasun S. Athukorala

AU - Slawin, Alexandra M. Z.

AU - Woollins, J. Derek

AU - Vargas-Baca, Ignacio

PY - 2013

Y1 - 2013

N2 - Oxidation of alkali metal derivatives of [Te((BuN)-Bu-t) P(mu-(NBu)-Bu-t)(2)P((NBu)-Bu-t)Te](2-)with I-2 produces the intermediate ditelluride dianion [Te((BuN)-Bu-t)P(mu-(NBu)-Bu-t)(2)P((NBu)-Bu-t)Te](2)(2-) with a planar PTeTeP conformation and, subsequently, the cyclic tritelluride [((BuN)-Bu-t)P(mu-(NBu)-Bu-t)(2)P((NBu)-Bu-t)(mu-TeTeTe)].

AB - Oxidation of alkali metal derivatives of [Te((BuN)-Bu-t) P(mu-(NBu)-Bu-t)(2)P((NBu)-Bu-t)Te](2-)with I-2 produces the intermediate ditelluride dianion [Te((BuN)-Bu-t)P(mu-(NBu)-Bu-t)(2)P((NBu)-Bu-t)Te](2)(2-) with a planar PTeTeP conformation and, subsequently, the cyclic tritelluride [((BuN)-Bu-t)P(mu-(NBu)-Bu-t)(2)P((NBu)-Bu-t)(mu-TeTeTe)].

KW - X-ray structure

KW - Crystal structure

KW - Macrocycles

KW - Anion

U2 - 10.1039/c2dt32716c

DO - 10.1039/c2dt32716c

M3 - Article

SN - 1477-9226

VL - 42

SP - 3291

EP - 3294

JO - Dalton Transactions

JF - Dalton Transactions

IS - 10

ER -

A planar dianionic ditelluride and a cyclic tritelluride supported by P2N2 rings

Abstract

Keywords

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