A novel polyoxo(thio)molybdenum(V) sulfite compound: synthesis and crystal structure of {[Mo2V(μ-S)2O2]63-SO3)4(μ-SO3)12}20- anion

HN Miras, John Derek Woollins, Alexandra Martha Zoya Slawin, R Raptis, P Baran, TA Kabanos

Research output: Contribution to journalArticlepeer-review

18 Citations (Scopus)

Abstract

The non-cyclic polyoxo(thio) molybdate(V)-sulfite K-6(NH4)(14){[Mo-2(V)(mu-S)(2)O-2](6)(mu(3)-SO3)(4)(mu-SO3)(12)} . 7H(2)O 1 was prepared by self-condensation of [Mo-2(V)(mu-S)(2)O-2](2+) building block in the presence of (NH4)(2)SO3. Compound 1 was characterized by X-ray structure analysis as well as IR, UV-vis spectroscopies and thermogravimetric analysis.

Original languageEnglish
Pages (from-to)3668-3670
Number of pages3
JournalDalton Transactions
Issue number19
DOIs
Publication statusPublished - 2003

Keywords

  • SOLID-STATE
  • MO
  • TETRAOXOIODATE(V)
  • CHEMISTRY

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