A novel polyoxo(thio)molybdenum(V) sulfite compound: synthesis and crystal structure of {[Mo2V(μ-S)2O2]6(μ3-SO3)4(μ-SO3)12}20- anion

HN Miras; John Derek Woollins; Alexandra Martha Zoya Slawin; R Raptis; P Baran; TA Kabanos

doi:10.1039/b309473c

A novel polyoxo(thio)molybdenum(V) sulfite compound: synthesis and crystal structure of {[Mo₂^V(μ-S)₂O₂]₆(μ₃-SO₃)₄(μ-SO₃)₁₂}^20- anion

HN Miras, John Derek Woollins, Alexandra Martha Zoya Slawin, R Raptis, P Baran, TA Kabanos

Research output: Contribution to journal › Article › peer-review

Abstract

The non-cyclic polyoxo(thio) molybdate(V)-sulfite K-6(NH4)(14){[Mo-2(V)(mu-S)(2)O-2](6)(mu(3)-SO3)(4)(mu-SO3)(12)} . 7H(2)O 1 was prepared by self-condensation of [Mo-2(V)(mu-S)(2)O-2](2+) building block in the presence of (NH4)(2)SO3. Compound 1 was characterized by X-ray structure analysis as well as IR, UV-vis spectroscopies and thermogravimetric analysis.

Original language	English
Pages (from-to)	3668-3670
Number of pages	3
Journal	Dalton Transactions
Issue number	19
DOIs	https://doi.org/10.1039/b309473c
Publication status	Published - 2003

Keywords

SOLID-STATE
MO
TETRAOXOIODATE(V)
CHEMISTRY

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title = "A novel polyoxo(thio)molybdenum(V) sulfite compound: synthesis and crystal structure of {[Mo2V(μ-S)2O2]6(μ3-SO3)4(μ-SO3)12}20- anion",

abstract = "The non-cyclic polyoxo(thio) molybdate(V)-sulfite K-6(NH4)(14){[Mo-2(V)(mu-S)(2)O-2](6)(mu(3)-SO3)(4)(mu-SO3)(12)} . 7H(2)O 1 was prepared by self-condensation of [Mo-2(V)(mu-S)(2)O-2](2+) building block in the presence of (NH4)(2)SO3. Compound 1 was characterized by X-ray structure analysis as well as IR, UV-vis spectroscopies and thermogravimetric analysis.",

keywords = "SOLID-STATE, MO, TETRAOXOIODATE(V), CHEMISTRY",

author = "HN Miras and Woollins, {John Derek} and Slawin, {Alexandra Martha Zoya} and R Raptis and P Baran and TA Kabanos",

year = "2003",

doi = "10.1039/b309473c",

language = "English",

pages = "3668--3670",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "ROYAL SOC CHEMISTRY",

number = "19",

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T1 - A novel polyoxo(thio)molybdenum(V) sulfite compound: synthesis and crystal structure of {[Mo2V(μ-S)2O2]6(μ3-SO3)4(μ-SO3)12}20- anion

AU - Miras, HN

AU - Woollins, John Derek

AU - Slawin, Alexandra Martha Zoya

AU - Raptis, R

AU - Baran, P

AU - Kabanos, TA

PY - 2003

Y1 - 2003

N2 - The non-cyclic polyoxo(thio) molybdate(V)-sulfite K-6(NH4)(14){[Mo-2(V)(mu-S)(2)O-2](6)(mu(3)-SO3)(4)(mu-SO3)(12)} . 7H(2)O 1 was prepared by self-condensation of [Mo-2(V)(mu-S)(2)O-2](2+) building block in the presence of (NH4)(2)SO3. Compound 1 was characterized by X-ray structure analysis as well as IR, UV-vis spectroscopies and thermogravimetric analysis.

AB - The non-cyclic polyoxo(thio) molybdate(V)-sulfite K-6(NH4)(14){[Mo-2(V)(mu-S)(2)O-2](6)(mu(3)-SO3)(4)(mu-SO3)(12)} . 7H(2)O 1 was prepared by self-condensation of [Mo-2(V)(mu-S)(2)O-2](2+) building block in the presence of (NH4)(2)SO3. Compound 1 was characterized by X-ray structure analysis as well as IR, UV-vis spectroscopies and thermogravimetric analysis.

KW - SOLID-STATE

KW - MO

KW - TETRAOXOIODATE(V)

KW - CHEMISTRY

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U2 - 10.1039/b309473c

DO - 10.1039/b309473c

M3 - Article

SN - 1477-9226

SP - 3668

EP - 3670

JO - Dalton Transactions

JF - Dalton Transactions

IS - 19

ER -

A novel polyoxo(thio)molybdenum(V) sulfite compound: synthesis and crystal structure of {[Mo₂^V(μ-S)₂O₂]₆(μ₃-SO₃)₄(μ-SO₃)₁₂}^20- anion

Abstract

Keywords

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