A novel non-centrosymmetric metallophosphate-borate compound via ionothermal synthesis

Zhuojia Lin; David S. Wragg; Philip Lightfoot; Russell E. Morris

doi:10.1039/b904450g

A novel non-centrosymmetric metallophosphate-borate compound via ionothermal synthesis

Zhuojia Lin, David S. Wragg, Philip Lightfoot, Russell E. Morris

Research output: Contribution to journal › Article › peer-review

Abstract

Ionothermal synthesis using a deep eutectic solvent has been used for the first time to prepare a borate-containing material. The metallophosphate-borate compound crystallises in chiral space group I222. Two different alkyl ammonium cations derived from the ionic liquid have distinct template effects on the formation of cobalt phosphate layers and hydrophobic borate channels.

Original language	English
Pages (from-to)	5287-5289
Number of pages	3
Journal	Dalton Transactions
Issue number	27
DOIs	https://doi.org/10.1039/b904450g
Publication status	Published - 2009

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title = "A novel non-centrosymmetric metallophosphate-borate compound via ionothermal synthesis",

abstract = "Ionothermal synthesis using a deep eutectic solvent has been used for the first time to prepare a borate-containing material. The metallophosphate-borate compound crystallises in chiral space group I222. Two different alkyl ammonium cations derived from the ionic liquid have distinct template effects on the formation of cobalt phosphate layers and hydrophobic borate channels.",

author = "Zhuojia Lin and Wragg, {David S.} and Philip Lightfoot and Morris, {Russell E.}",

year = "2009",

doi = "10.1039/b904450g",

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T1 - A novel non-centrosymmetric metallophosphate-borate compound via ionothermal synthesis

AU - Lin, Zhuojia

AU - Wragg, David S.

AU - Lightfoot, Philip

AU - Morris, Russell E.

PY - 2009

Y1 - 2009

N2 - Ionothermal synthesis using a deep eutectic solvent has been used for the first time to prepare a borate-containing material. The metallophosphate-borate compound crystallises in chiral space group I222. Two different alkyl ammonium cations derived from the ionic liquid have distinct template effects on the formation of cobalt phosphate layers and hydrophobic borate channels.

AB - Ionothermal synthesis using a deep eutectic solvent has been used for the first time to prepare a borate-containing material. The metallophosphate-borate compound crystallises in chiral space group I222. Two different alkyl ammonium cations derived from the ionic liquid have distinct template effects on the formation of cobalt phosphate layers and hydrophobic borate channels.

U2 - 10.1039/b904450g

DO - 10.1039/b904450g

M3 - Article

SN - 1477-9226

SP - 5287

EP - 5289

JO - Dalton Transactions

JF - Dalton Transactions

IS - 27

ER -

A novel non-centrosymmetric metallophosphate-borate compound via ionothermal synthesis

Abstract

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