A novel copper oxalate, Na2Cu(C2O4)2

Wenjiao Yao; A. Robert Armstrong; Philip Lightfoot

doi:10.1002/zaac.201600320

A novel copper oxalate, Na₂Cu(C₂O₄)₂

Wenjiao Yao, A. Robert Armstrong, Philip Lightfoot

Research output: Contribution to journal › Article › peer-review

Abstract

A novel copper oxalate Na₂Cu(C₂O₄)₂ was synthesized through a hydrothermal method and characterized by single-crystal X-ray diffraction. It crystallizes in monoclinic system, P2₁/n space group with a = 72578(3) Å, b = 5.7711(4) Å, c = 8.6604(8) Å, β = 106.948(9)°. The structure displays a novel stacking pattern of [Cu(C₂O₄)₂]^2– units connected through electrostatic attraction by Na⁺ cations. Structural comparisons are made to related compounds.

Original language	English
Pages (from-to)	1345-1349
Number of pages	5
Journal	Zeitschrift für Anorganische und Allgemeine Chemie
Volume	642
Issue number	23
Early online date	28 Oct 2016
DOIs	https://doi.org/10.1002/zaac.201600320
Publication status	Published - 5 Dec 2016

Keywords

Copper oxalate
Hydrothermal synthesis
Single crystal structure
Powder X-ray diffraction

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10.1002/zaac.201600320

Na2Cu_submitted
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at: https://doi.org/10.1002/zaac.201600320
Accepted author manuscript, 1.21 MB

Design & synthesis of new fluoride: Design and synthesis of new fluoride cathode materials for solid-state batteries
Lightfoot, P. (PI)
The Royal Society
1/02/15 → 31/01/17
Project: Fellowship

A novel copper oxalate, Na2Cu(C2O4)2 (dataset)
Yao, W. (Creator), Armstrong, R. (Creator) & Lightfoot, P. (Creator), Cambridge Crystallographic Data Centre, 2020
https://dx.doi.org/10.5517/ccdc.csd.cc1lqg2v
Dataset

Cite this

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title = "A novel copper oxalate, Na2Cu(C2O4)2",

abstract = "A novel copper oxalate Na2Cu(C2O4)2 was synthesized through a hydrothermal method and characterized by single-crystal X-ray diffraction. It crystallizes in monoclinic system, P21/n space group with a = 72578(3) {\AA}, b = 5.7711(4) {\AA}, c = 8.6604(8) {\AA}, β = 106.948(9)°. The structure displays a novel stacking pattern of [Cu(C2O4)2]2– units connected through electrostatic attraction by Na+ cations. Structural comparisons are made to related compounds.",

keywords = "Copper oxalate, Hydrothermal synthesis, Single crystal structure, Powder X-ray diffraction",

author = "Wenjiao Yao and Armstrong, {A. Robert} and Philip Lightfoot",

note = "The authors thank the Royal Society for the award of a Newton Fellowship (NF140881) to W.Y.",

year = "2016",

month = dec,

day = "5",

doi = "10.1002/zaac.201600320",

language = "English",

volume = "642",

pages = "1345--1349",

journal = "Zeitschrift f{\"u}r Anorganische und Allgemeine Chemie",

issn = "1521-3749",

publisher = "Wiley-VCH, Weinheim",

number = "23",

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TY - JOUR

T1 - A novel copper oxalate, Na2Cu(C2O4)2

AU - Yao, Wenjiao

AU - Armstrong, A. Robert

AU - Lightfoot, Philip

N1 - The authors thank the Royal Society for the award of a Newton Fellowship (NF140881) to W.Y.

PY - 2016/12/5

Y1 - 2016/12/5

N2 - A novel copper oxalate Na2Cu(C2O4)2 was synthesized through a hydrothermal method and characterized by single-crystal X-ray diffraction. It crystallizes in monoclinic system, P21/n space group with a = 72578(3) Å, b = 5.7711(4) Å, c = 8.6604(8) Å, β = 106.948(9)°. The structure displays a novel stacking pattern of [Cu(C2O4)2]2– units connected through electrostatic attraction by Na+ cations. Structural comparisons are made to related compounds.

AB - A novel copper oxalate Na2Cu(C2O4)2 was synthesized through a hydrothermal method and characterized by single-crystal X-ray diffraction. It crystallizes in monoclinic system, P21/n space group with a = 72578(3) Å, b = 5.7711(4) Å, c = 8.6604(8) Å, β = 106.948(9)°. The structure displays a novel stacking pattern of [Cu(C2O4)2]2– units connected through electrostatic attraction by Na+ cations. Structural comparisons are made to related compounds.

KW - Copper oxalate

KW - Hydrothermal synthesis

KW - Single crystal structure

KW - Powder X-ray diffraction

U2 - 10.1002/zaac.201600320

DO - 10.1002/zaac.201600320

M3 - Article

SN - 1521-3749

VL - 642

SP - 1345

EP - 1349

JO - Zeitschrift für Anorganische und Allgemeine Chemie

JF - Zeitschrift für Anorganische und Allgemeine Chemie

IS - 23

ER -

A novel copper oxalate, Na2Cu(C2O4)2

Abstract

Keywords

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Projects

Design & synthesis of new fluoride: Design and synthesis of new fluoride cathode materials for solid-state batteries

Datasets

A novel copper oxalate, Na2Cu(C2O4)2 (dataset)

Cite this

A novel copper oxalate, Na₂Cu(C₂O₄)₂