A Novel Alanine Derivatised Phosphine

Alexandra Martha Zoya Slawin; John Derek Woollins; Q Zhang

A Novel Alanine Derivatised Phosphine

Alexandra Martha Zoya Slawin, John Derek Woollins, Q Zhang

Research output: Other contribution

15 Citations (Scopus)

Abstract

Reaction of Ph2PCl with alanine methyl ester affords the chiral aminophosphine Ph2NHCH(CH3)C(O) OCH3 (dppal) which reacts with M(COD)Cl-2 to give Pt(dppal)(2)Cl-2 (1) and Cl(dppal)PdCl2Pd(dppal)Cl (2). The X-ray structures of dppalO, 1 and 2 an reported. The amino acid containing ligand forms intramolecular H bonds with the C-O-C or C=O oxygen atoms within the ligand and with the cis chlorides in the complexes. (C) 1999 Elsevier Science S.A. All rights reserved.

Original language	English
Volume	2
Publication status	Published - Sept 1999

Keywords

crystal structures
alanine compounds
phosphine compounds

Cite this

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title = "A Novel Alanine Derivatised Phosphine",

abstract = "Reaction of Ph2PCl with alanine methyl ester affords the chiral aminophosphine Ph2NHCH(CH3)C(O) OCH3 (dppal) which reacts with M(COD)Cl-2 to give Pt(dppal)(2)Cl-2 (1) and Cl(dppal)PdCl2Pd(dppal)Cl (2). The X-ray structures of dppalO, 1 and 2 an reported. The amino acid containing ligand forms intramolecular H bonds with the C-O-C or C=O oxygen atoms within the ligand and with the cis chlorides in the complexes. (C) 1999 Elsevier Science S.A. All rights reserved.",

keywords = "crystal structures, alanine compounds, phosphine compounds",

author = "Slawin, {Alexandra Martha Zoya} and Woollins, {John Derek} and Q Zhang",

note = "Inorg Chem.Comm",

year = "1999",

month = sep,

language = "English",

volume = "2",

type = "Other",

}

TY - GEN

T1 - A Novel Alanine Derivatised Phosphine

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, John Derek

AU - Zhang, Q

N1 - Inorg Chem.Comm

PY - 1999/9

Y1 - 1999/9

N2 - Reaction of Ph2PCl with alanine methyl ester affords the chiral aminophosphine Ph2NHCH(CH3)C(O) OCH3 (dppal) which reacts with M(COD)Cl-2 to give Pt(dppal)(2)Cl-2 (1) and Cl(dppal)PdCl2Pd(dppal)Cl (2). The X-ray structures of dppalO, 1 and 2 an reported. The amino acid containing ligand forms intramolecular H bonds with the C-O-C or C=O oxygen atoms within the ligand and with the cis chlorides in the complexes. (C) 1999 Elsevier Science S.A. All rights reserved.

AB - Reaction of Ph2PCl with alanine methyl ester affords the chiral aminophosphine Ph2NHCH(CH3)C(O) OCH3 (dppal) which reacts with M(COD)Cl-2 to give Pt(dppal)(2)Cl-2 (1) and Cl(dppal)PdCl2Pd(dppal)Cl (2). The X-ray structures of dppalO, 1 and 2 an reported. The amino acid containing ligand forms intramolecular H bonds with the C-O-C or C=O oxygen atoms within the ligand and with the cis chlorides in the complexes. (C) 1999 Elsevier Science S.A. All rights reserved.

KW - crystal structures

KW - alanine compounds

KW - phosphine compounds

UR - http://www.scopus.com/inward/record.url?scp=0007323234&partnerID=8YFLogxK

M3 - Other contribution

VL - 2

ER -

A Novel Alanine Derivatised Phosphine

Abstract

Keywords

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